- 专利标题: Nickel manganese composite hydroxide particles and manufacturing method thereof, cathode active material for a non-aqueous electrolyte secondary battery and manufacturing method thereof, and a non-aqueous electrolyte secondary battery
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申请号: US15989147申请日: 2018-05-24
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公开(公告)号: US10669646B2公开(公告)日: 2020-06-02
- 发明人: Hiroyuki Toya , Kensaku Mori , Shin Imaizumi , Kenji Ikeuchi , Toshiyuki Osako
- 申请人: SUMITO METAL MINING CO., LTD.
- 申请人地址: JP Tokyo
- 专利权人: SUMITOMO METAL MINING CO., LTD.
- 当前专利权人: SUMITOMO METAL MINING CO., LTD.
- 当前专利权人地址: JP Tokyo
- 代理机构: Locke Lord LLP
- 代理商 James E. Armstrong, IV; Nicholas J. DiCeglie, Jr.
- 主分类号: H01M4/525
- IPC分类号: H01M4/525 ; C30B7/14 ; H01M4/505 ; C01G53/00 ; H01M4/04 ; H01M4/36 ; H01M10/0525
摘要:
Provided are nickel manganese composite hydroxide particles having a small and uniform particle size and having a double structure which enables to obtain a cathode active material having a hollow structure, and a manufacturing method thereof. When obtaining the nickel manganese composite hydroxide by a reaction crystallization, using an aqueous solution for nucleation, which includes at least a metallic compound that contains nickel, a metallic compound that contains manganese and an ammonium ion donor and controlling the pH value that is measured at a standard solution temperature of 25° C. is 10.5 to 12.0, nucleation is performed in an oxidizing atmosphere in which the oxygen concentration is greater than 1% by volume, and then nuclei are grown by switching the atmosphere from the oxidizing atmosphere to a mixed atmosphere of oxygen and inert gas in which the oxygen concentration is 1% by volume or less.
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