A charging rescue system and method for all-electric vehicles comprises: a rescue vehicle APP, a charging rescue vehicle, a rescued vehicle APP, and a rescue platform. The rescue vehicle APP comprises a user module, an order module, a monitoring module, and a communication module. The charging rescue vehicle comprises a controller, a GPS device, a direct current battery charger, an alternating current battery charger, and a measuring module. The rescued vehicle APP comprises a user module, an order module, a payment module, and a communication module. The rescue platform comprises an access module, an order execution module, a vehicle selection module, a rescue vehicle monitoring module, a bill management module, and a user authentication module.