Invention Grant
- Patent Title: Lithium metal oxide cathode powders for high voltage lithium-ion batteries
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Application No.: US15545348Application Date: 2016-01-20
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Publication No.: US10854874B2Publication Date: 2020-12-01
- Inventor: Xin Xia , Jens Paulsen , Shinichi Kumakura , Song-Yi Han
- Applicant: Umicore , Umicore Korea Ltd.
- Applicant Address: BE Brussels KR Chungnam
- Assignee: Umicore,Umicore Korea Ltd.
- Current Assignee: Umicore,Umicore Korea Ltd.
- Current Assignee Address: BE Brussels KR Chungnam
- Agency: NK Patent Law
- Priority: EP15152336 20150123
- International Application: PCT/IB2016/050262 WO 20160120
- International Announcement: WO2016/116867 WO 20160728
- Main IPC: H01M4/36
- IPC: H01M4/36 ; H01M4/525 ; H01M4/1391 ; H01M4/04 ; H01M4/131 ; H01M4/505 ; H01M10/0525 ; H01M4/02 ; C01G53/00

Abstract:
This invention discloses a lithium metal oxide powder for a cathode material in a rechargeable battery, consisting of a core and a surface layer, the core having a layered crystal structure comprising the elements Li, M and oxygen, wherein M has the formula M=(Niz(Ni1/2Mn1/2)yCox)1-kAk, with 0.15≤x≤0.30, 0.20≤z≤0.55, x+y+z=1 and 0≤k≤0.1, wherein A is a dopant, wherein the Li content is stoichiometrically controlled with a molar ratio 0.95≤Li:M≤1.10; and wherein the surface layer comprises the elements Li, M′ and oxygen, wherein M′ has the formula M′=(Niz′(Ni1/2Mn1/2)y′Cox′)1-k′Ak′, with x′+y′+z′=1 and 0≤k′≤0.1, and wherein y′/(y′+2z′)≥1.1*[y/(y+2z)]. The surface layer may also comprise at least 3 mol % Al, the Al content in the surface layer 10 being determined by XPS.
Public/Granted literature
- US20180034045A1 Lithium Metal Oxide Cathode Powders for High Voltage Lithium-Ion Batteries Public/Granted day:2018-02-01
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