- 专利标题: Mixture of polymerizable compound and method of producing the same
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申请号: US16744489申请日: 2020-01-16
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公开(公告)号: US10934246B2公开(公告)日: 2021-03-02
- 发明人: Kei Sakamoto , Kumi Okuyama , Kanako Sanuki
- 申请人: ZEON CORPORATION
- 申请人地址: JP Tokyo
- 专利权人: ZEON CORPORATION
- 当前专利权人: ZEON CORPORATION
- 当前专利权人地址: JP Tokyo
- 优先权: JPJP2015-072950 20150331
- 主分类号: C07C67/58
- IPC分类号: C07C67/58 ; C07C67/14 ; C07C69/75 ; C07D277/82 ; G02B5/30 ; C07C69/017 ; C07C67/08 ; C07C67/52 ; G02B1/08
摘要:
Disclosed is a mixture containing compound (I) and polymerizable compound (II) wherein compound (I) accounts for 50 mol % or more of the entire mixture and 1,4-cyclohexanedicarboxylic acid accounts for less than 5 mol % of the entire mixture; a method of producing the mixture which includes reacting in a water-immiscible organic solvent 1,4-cyclohexanedicarboxylic acid dichloride with compound (IV) in the presence of a base, and washing the obtained reaction solution with a weakly acidic buffer solution; etc. The disclosure provides mixtures useful for low-cost production of polymerizable compounds which have low melting points suitable for practical use, show superior solubility to general-purpose solvents, can be produced at low costs, and allow for provision of optical films capable of uniform polarized light conversion over a wide wavelength range, and methods of producing the mixtures. where A represents hydrogen, methyl group or chlorine, and n represents an integer of 1 to 20.
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