公开(公告)号：US20150274872A1

公开(公告)日：2015-10-01

申请号：US14437748

申请日：2013-10-16

申请人： ZEON CORPORATION

发明人： Kei Sakamoto ,  Satoshi Kiriki ,  Kumi Okuyama

IPC分类号： C08F222/24 ,  G02B1/04 ,  C07D277/50

CPC分类号： C08F222/24 ,  C07D277/20 ,  C07D277/50 ,  C08F222/1006 ,  G02B1/04 ,  G02B1/08 ,  G02B5/3016 ,  G02F2001/133633

摘要： The present invention pertains to: a polymerizable compound represented by a formula (I); a polymerizable composition comprising the polymerizable compound and an initiator; a polymer obtained by polymerizing the polymerizable compound or the polymerizable composition; and an optically anisotropic article comprising the polymer. The present invention provides a polymerizable compound, a polymerizable composition, and a polymer that have a practical low melting point, exhibit excellent solubility in a general-purpose solvent, can be produced at low cost, and can produce an optical film that achieves uniform conversion of polarized light over a wide wavelength band, and also provide an optically anisotropic article. [In the formula: Y1 to Y8 are a chemical single bond, —O—, —O—C(═O)—, —O—C(═O)—O—, etc.; G1 and G2 are a divalent aliphatic group having 1 to 20 carbon atoms, etc.; Z1 and Z2 are an alkenyl group having 2 to 10 carbon atoms that is substituted with a halogen atom, or unsubstituted, etc.; Ax is a group represented by a formula (II), wherein X is a nitrogen atom, etc.; Ra and Rb are a hydrogen atom, an aromatic hydrocarbon ring group having 1 to 20 carbon atoms, etc.; Ay is a hydrogen atom, the group represented by the formula (II), etc.; A1 is a trivalent aromatic group, etc; A2 and A3 are a divalent alicyclic hydrocarbon group having 3 to 30 carbon atoms, etc.; A4 and A5 are a divalent aromatic group having 4 to 30 carbon atoms, etc.; Q1 is a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, etc.]

摘要翻译： 本发明涉及：由式（I）表示的可聚合化合物; 包含可聚合化合物和引发剂的可聚合组合物; 通过聚合可聚合化合物或可聚合组合物而获得的聚合物; 和包含聚合物的光学各向异性制品。 本发明提供一种具有实用低熔点，在通用溶剂中表现出优异溶解性的聚合性化合物，聚合性组合物和聚合物，可以制造出低成本的光学膜， 的偏振光，并且还提供光学各向异性制品。 [式中，Y1〜Y8为化学单键，-O - ， - O-C（= O） - ， - O-C（= O）-O-等。 G1和G2是具有1至20个碳原子的二价脂族基团等; Z1和Z2是被卤素原子取代的具有2-10个碳原子的烯基，或未被取代的; Ax是由式（II）表示的基团，其中X是氮原子等; Ra和Rb是氢原子，碳原子数1〜20的芳香族烃环基等。 Ay是氢原子，由式（II）表示的基团等; A1是三价芳族基团等; A2和A3是具有3至30个碳原子的二价脂环族烃基等; A4和A5是碳原子数为4〜30的二价芳香族基团等。 Q1是氢原子，碳原子数1〜6的烷基等]

公开(公告)号：US10577306B2

公开(公告)日：2020-03-03

申请号：US15560646

申请日：2016-03-30

申请人： ZEON CORPORATION

发明人： Kei Sakamoto ,  Kumi Okuyama ,  Kanako Sanuki

IPC分类号： C07C67/58 ,  C07C67/14 ,  C07C69/75 ,  C07D277/82 ,  G02B5/30 ,  C07C69/017 ,  C07C67/08 ,  C07C67/52 ,  G02B1/08

摘要： Disclosed is a mixture containing compound (I) and polymerizable compound (II) wherein compound (I) accounts for 50 mol % or more of the entire mixture and 1,4-cyclohexanedicarboxylic acid accounts for less than 5 mol % of the entire mixture; a method of producing the mixture which includes reacting in a water-immiscible organic solvent 1,4-cyclohexanedicarboxylic acid dichloride with compound (IV) in the presence of a base, and washing the obtained reaction solution with a weakly acidic buffer solution; etc. The disclosure provides mixtures useful for low-cost production of polymerizable compounds which have low melting points suitable for practical use, show superior solubility to general-purpose solvents, can be produced at low costs, and allow for provision of optical films capable of uniform polarized light conversion over a wide wavelength range, and methods of producing the mixtures. where A represents hydrogen, methyl group or chlorine, and n represents an integer of 1 to 20.

公开(公告)号：US10059679B2

公开(公告)日：2018-08-28

申请号：US15124092

申请日：2015-03-19

申请人： ZEON CORPORATION

发明人： Kumi Okuyama ,  Kanako Sanuki ,  Kei Sakamoto

IPC分类号： C07D277/82 ,  C08F22/26 ,  C07C69/757 ,  C07C69/75 ,  C07C67/14

CPC分类号： C07D277/82 ,  C07C67/14 ,  C07C69/75 ,  C07C69/757 ,  C07C2601/14 ,  C08F22/22 ,  C08F22/26

摘要： Provided is a method for producing a polymerizable compound represented by a formula (I) comprising: a step (1) that reacts a compound represented by a formula (II) with 2,5-dihydroxybenzaldehyde in an organic solvent in the presence of a base to obtain a reaction mixture including a compound represented by a formula (III); and a step (2) that adds a compound represented by a formula (IV) and an acidic aqueous solution to the reaction mixture obtained by the step (1) to effect a reaction, wherein A represents a hydrogen atom, a methyl group or the like, L represents a leaving group, n represents an integer from 1 to 20, X represents an oxygen atom, a sulfur atom, —C(R1)(R2)— or the like, R represents a hydrogen atom, an organic group or the like, and each of RX represents a hydrogen atom, a halogen atom or the like. According to the present invention, provided is a method for producing a polymerizable compound represented by a formula (I) at high purity and at high yield.

公开(公告)号：US09868710B2

公开(公告)日：2018-01-16

申请号：US15032120

申请日：2014-10-30

申请人： ZEON CORPORATION

发明人： Kei Sakamoto ,  Kumi Okuyama

IPC分类号： C07D277/62 ,  C07D277/82 ,  C07C251/82 ,  C07C251/86 ,  G02B5/30 ,  C08F222/10 ,  C09K19/38 ,  G02B1/111

CPC分类号： C07D277/82 ,  C07C251/82 ,  C07C251/86 ,  C07D277/62 ,  C08F222/1006 ,  C09K19/3838 ,  G02B1/111 ,  G02B5/30

摘要： This invention provides a polymerizable compound represented by formula (I), a polymerizable composition containing the polymerizable compound and a polymerization initiator, a polymer produced by polymerizing the polymerizable compound or the polymerizable composition, and an optically anisotropic product comprising the polymer as a constituent material. In formula (1), Y1 to Y9 represent —O—, —S—, —O—C(═O)—, —C(═O)—O— or the like, G1 and G2 represent a divalent linear aliphatic group having 1 to 20 carbon atoms or the like, Z1 to Z3 represent an alkenyl group having 2 to 10 carbon atoms or the like, Ax represents a group represented by a formula (II), wherein X represents an oxygen atom, a sulfur atom or the like,D represents an alkylene group having 1 to 20 carbon atoms or the like, A1 represents a trivalent aromatic group or the like, A2 and A3 represent a divalent alicyclic hydrocarbon group having 3 to 30 carbon atoms or the like, A4 and A5 represent a divalent aromatic group having 4 to 30 carbon atoms or the like, Q1 represents an alkyl group having 1 to 6 carbon atoms or the like, and m and n are 0 or 1.

公开(公告)号：US20150183902A1

公开(公告)日：2015-07-02

申请号：US14404723

申请日：2013-05-30

申请人： ZEON CORPORATION

发明人： Kei Sakamoto ,  Kumi Okuyama

IPC分类号： C08F122/24 ,  G02B1/08 ,  C08F222/24 ,  C07D513/04 ,  C07D277/82

CPC分类号： C08F22/24 ,  C07D277/82 ,  C07D513/04 ,  C08F122/24 ,  C08F222/24 ,  C08F2222/102 ,  C09K19/24 ,  C09K19/322 ,  C09K19/348 ,  C09K19/3486 ,  C09K19/3488 ,  C09K19/3497 ,  C09K19/3852 ,  C09K19/3861 ,  C09K2019/0448 ,  C09K2019/2078 ,  G02B1/08 ,  G02B5/3016 ,  G02B5/3025

摘要： The present invention relates to: a polymerizable compound (I), wherein Y1 to Y6 are a chemical single bond, —O—C(═O)—, —C(═O)—O— or the like, G1 and G2 are a divalent aliphatic group, Z1 and Z2 are an alkenyl group, Ax is a fused ring group represented by a formula (II), wherein X is —NR3—, an oxygen atom, a sulfur atom or the like, R3 is a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, and D is a substituted or unsubstituted ring having 1 to 20 carbon atoms that includes at least one nitrogen atom, Ay is a hydrogen atom, an alkyl group, A1 is a trivalent aromatic group or the like, A2 and A3 are a divalent aromatic group having 6 to 30 carbon atoms or the like, and Q1 is a hydrogen atom, or an alkyl group having 1 to 6 carbon atoms.

摘要翻译： 本发明涉及：可聚合化合物（I），其中Y 1至Y 6是化学单键，-O-C（= O） - ， - C（= O）-O-等，G 1和G 2是 二价脂族基团，Z 1和Z 2为烯基，Ax为式（II）所示的稠环基团，其中X为-NR 3 - ，氧原子，硫原子等，R 3为氢原子 或具有1〜6个碳原子的烷基，D为具有1〜20个碳原子的取代或未取代的环，其包含至少一个氮原子，Ay为氢原子，烷基，Al为三价芳基或 A2，A3为碳原子数为6〜30的二价芳香族基团，Q1为氢原子或碳原子数为1〜6的烷基。

公开(公告)号：US11091452B2

公开(公告)日：2021-08-17

申请号：US16595538

申请日：2019-10-08

申请人： ZEON CORPORATION

发明人： Kei Sakamoto ,  Satoshi Kiriki ,  Kumi Okuyama ,  Kanako Taira

IPC分类号： C07C243/18 ,  C07D277/82 ,  C07D417/12 ,  C07D277/84 ,  C07D513/04 ,  C08F20/36 ,  C07C243/16 ,  C07C243/20 ,  C07C243/14 ,  C07C69/753 ,  C08F22/24 ,  C09K19/04 ,  C08F28/06 ,  C08F22/14 ,  C08F22/20 ,  C08F20/68 ,  C08F22/26 ,  C08F22/22 ,  C08F26/06 ,  C07C251/86 ,  G02F1/137 ,  C07C249/16 ,  G02B5/30 ,  C08F22/10

摘要： A polymerizable compound has a practical low melting point, excellent solubility in a general-purpose solvent, and can produce an optical film at low cost, exhibits low reflected luminance, and achieves uniform conversion of polarized light over a wide wavelength band, an optically anisotropic article.

公开(公告)号：US10647794B2

公开(公告)日：2020-05-12

申请号：US14920294

申请日：2015-10-22

申请人： ZEON CORPORATION

发明人： Kei Sakamoto ,  Kumi Okuyama

IPC分类号： C07D215/38 ,  C08F122/24 ,  C07D237/34 ,  C07D263/58 ,  C07D277/82 ,  C08F222/10 ,  C07C251/86 ,  C08F220/34 ,  C07D487/04 ,  G02B1/08 ,  C07C69/92 ,  C07C243/20 ,  C08F122/22 ,  G02B5/30

摘要： The invention provides a polymerizable compound of formula (I), polymerizable composition, polymer, and optically anisotropic article capable of obtaining an optical film having a low melting point, excellent solubility, being manufactured at low cost, and of uniform polarized light conversion across a broad wavelength region. In formula (I): Y1 to Y6 are independently a chemical single bond, —O—, —O—C(═O)—, —C(═O)—O—; G1 and G2 are independently a divalent C1-C20 aliphatic group; Z1 and Z2 are independently a C2-C10 alkenyl group substituted with a halogen atom; Ax is a C2-C30 organic group that includes at least one aromatic ring of an aromatic hydrocarbon ring or an aromatic hetero ring; Ay is H, a C1-C20 alkyl group, a C2-C20 alkenyl group, a C3-C12 cycloalkyl group; A1 is a trivalent aromatic group; A2 and A3 are independently a divalent C6-C30 aromatic group; and Q1 is H, or a C1-C6 alkyl group.

公开(公告)号：US10400170B2

公开(公告)日：2019-09-03

申请号：US15115987

申请日：2015-02-09

申请人： ZEON CORPORATION

发明人： Kei Sakamoto ,  Kumi Okuyama

IPC分类号： G02F1/1333 ,  C09K19/38 ,  C07C251/68 ,  C08F20/36 ,  G02B5/30 ,  C08F222/10 ,  C07C229/36 ,  C08G73/02 ,  G02B1/04 ,  G02B5/00

摘要： This polymerizable compound is represented by a formula (I), this polymerizable composition contains said polymerizable compound and a polymerization initiator, this polymer is obtained by polymerizing the polymerizable compound or polymerizable composition, and this optically anisotropic product is comprised from the polymer. In the formula, each of Y1 to Y8 represents —O—, —S—, —O—C(═O)—, —C(═O)—O—, etc., Ya represents —O—, —S—, —O—C(═O)—, —C(═O)—O—, etc., each of G1 and G2 represents a divalent linear aliphatic group having 1 to 20 carbon atoms, etc., each of Z1 and Z2 represents an alkenyl group having 2 to 10 carbon atoms, etc., Ax represents an organic group having an aromatic ring and 2 to 30 carbon atoms, A1 represents a trivalent aromatic group, etc., each of A2 and A3 represents a divalent alicyclic hydrocarbon group having 3 to 30 carbon atoms, each of A4 and A5 represents a divalent aromatic group having 4 to 30 carbon atoms, etc., Q1 represents an alkyl group having 1 to 6 carbon atoms, etc., and each of m and n represents 0 or 1.

公开(公告)号：US10227292B2

公开(公告)日：2019-03-12

申请号：US14768016

申请日：2014-02-12

申请人： ZEON CORPORATION

发明人： Kei Sakamoto ,  Satoshi Kiriki ,  Kumi Okuyama ,  Kanako Sanuki

IPC分类号： C09K19/38 ,  G02B5/30 ,  C08F22/10 ,  C09K19/04 ,  C09K19/30 ,  C09K19/32 ,  C09K19/34 ,  C07C251/88 ,  C07D277/82 ,  C08F128/06 ,  C08F222/10

摘要： A polymerizable compound, a polymerizable composition, and a polymer, which have a low melting point at a practical level and exhibit excellent solubility in a general-purpose solvent, can be produced at low cost. The polymerizable compound, polymerizable composition, and polymer can produce an optical film, which exhibits excellent transparency and achieves uniform conversion of polarized light over a wide wavelength band, and an optically anisotropic article. The polymerizable compound is represented by formula (I).

公开(公告)号：US09512251B2

公开(公告)日：2016-12-06

申请号：US14404723

申请日：2013-05-30

申请人： ZEON CORPORATION

发明人： Kei Sakamoto ,  Kumi Okuyama

IPC分类号： C08F122/24 ,  G02B1/08 ,  C08F222/24 ,  C07D513/04 ,  C07D277/82 ,  C09K19/24 ,  C09K19/32 ,  C09K19/34 ,  C09K19/38 ,  G02B5/30 ,  C09K19/04 ,  C09K19/20 ,  C08F222/10

CPC分类号： C08F22/24 ,  C07D277/82 ,  C07D513/04 ,  C08F122/24 ,  C08F222/24 ,  C08F2222/102 ,  C09K19/24 ,  C09K19/322 ,  C09K19/348 ,  C09K19/3486 ,  C09K19/3488 ,  C09K19/3497 ,  C09K19/3852 ,  C09K19/3861 ,  C09K2019/0448 ,  C09K2019/2078 ,  G02B1/08 ,  G02B5/3016 ,  G02B5/3025

摘要： The present invention relates to: a polymerizable compound (I), wherein Y1 to Y6 are a chemical single bond, —O—C(═O)—, —C(═O)—O— or the like, G1 and G2 are a divalent aliphatic group, Z1 and Z2 are an alkenyl group, Ax is a fused ring group represented by a formula (II), wherein X is —NR3—, an oxygen atom, a sulfur atom or the like, R3 is a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, and D is a substituted or unsubstituted ring having 1 to 20 carbon atoms that includes at least one nitrogen atom, Ay is a hydrogen atom, an alkyl group, A1 is a trivalent aromatic group or the like, A2 and A3 are a divalent aromatic group having 6 to 30 carbon atoms or the like, and Q1 is a hydrogen atom, or an alkyl group having 1 to 6 carbon atoms.

摘要翻译： 本发明涉及：可聚合化合物（1），其中Y 1至Y 6为化学单键，-OC（= O） - ， - C（= O）-O-等，G 1和G 2为碳原子数为1〜20的二价脂肪族基团，Z 1和Z 2为未取代或被卤素原子取代的碳原子数2〜10的烯基，A x为 式（II）其中X为-NR 3 - ，氧原子，硫原子等，R 3为氢原子或碳原子数1〜6的烷基，D为取代或未取代的环 具有1至20个碳原子，包括至少一个氮原子，A y是氢原子，具有1至20个碳原子的烷基等，A 1是三价芳族基团等，A 2和A 3 是碳原子数为6〜30的二价芳香族基团，Q 1为氢原子或碳原子数为1〜6的烷基。 本发明提供一种具有实用低熔点，在通用溶剂中表现出优异溶解性的聚合性化合物，聚合性组合物和聚合物，可以制造出低成本的光学膜， 在宽波长带上的偏振光，以及光学各向异性物品。