Disclosed is a steel sheet having a predetermined chemical composition and a steel microstructure that contains, in area ratio, 35% or more and 80% or less of polygonal ferrite and 5% or more and 25% or less of martensite, and that contains, in volume fraction, 8% or more of retained austenite, in which the polygonal ferrite, the martensite, and the retained austenite have a mean grain size of 6 μm or less, 3 μm or less, and 3 μm or less, respectively, and each have a mean grain aspect ratio of 2.0 or less, and in which a value obtained by dividing an Mn content in the retained austenite in mass % by an Mn content in the polygonal ferrite in mass % equals 2.0 or more.