Invention Grant
- Patent Title: Process to produce modified clay, supported metallocene polymerization catalyst
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Application No.: US15572658Application Date: 2016-05-09
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Publication No.: US10982023B2Publication Date: 2021-04-20
- Inventor: Michael D. Jensen , John Robert McCauley , Andrew G. Singleton , Demetrius Michos
- Applicant: W. R. Grace & Co.-Conn.
- Applicant Address: US MD Columbia
- Assignee: W. R. Grace & Co.-Conn.
- Current Assignee: W. R. Grace & Co.-Conn.
- Current Assignee Address: US MD Columbia
- Agency: Lerner, David, Littenberg, Krumholz & Mentlik, LLP
- International Application: PCT/US2016/031464 WO 20160509
- International Announcement: WO2016/183006 WO 20161117
- Main IPC: C08F10/02
- IPC: C08F10/02 ; B01J31/16 ; B01J31/00 ; B01J31/22 ; B01J31/14 ; C08F4/6592

Abstract:
Catalyst support-activator for olefin polymerization catalysts, and processes for making, the support-activator comprising an intercalated, modified and calcined smectite clay comprising (a) pillars comprising aluminum and optionally: (i) at least one rare earth or lanthanide group metal; or (ii) at least one rare earth or lanthanide group metal and gallium; and (b) at least one ion-exchanged metal ion selected from the group consisting of aluminum, barium, beryllium, calcium, cerium, cesium, copper, chromium, gadolinium, gallium, germanium, hafnium, holmium, iron (II and III), lanthanum, lithium, magnesium, manganese, neodymium, potassium, praseodymium, rubidium, samarium, silver, selenium, sodium, strontium, tellurium, terbium, thallium, thorium, tin, titanium, uranium, ytterbium, yttrium, zinc and zirconium. The pillared clay exhibits a basal d100 spacing of: (A) 9 to 18 angstroms; or (B) equal to or greater than about 18.5 angstroms. Use of the modified clays, with metallocene catalyst precursor components, provides active olefin polymerization catalysts, preferably in the substantial absence of aluminoxanes or boron-containing compounds.
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