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公开(公告)号：US10982023B2
公开(公告)日：2021-04-20
申请号：US15572658
申请日：2016-05-09
Applicant: W. R. Grace & Co.-Conn.
Inventor： Michael D. Jensen , John Robert McCauley , Andrew G. Singleton , Demetrius Michos
Abstract: Catalyst support-activator for olefin polymerization catalysts, and processes for making, the support-activator comprising an intercalated, modified and calcined smectite clay comprising (a) pillars comprising aluminum and optionally: (i) at least one rare earth or lanthanide group metal; or (ii) at least one rare earth or lanthanide group metal and gallium; and (b) at least one ion-exchanged metal ion selected from the group consisting of aluminum, barium, beryllium, calcium, cerium, cesium, copper, chromium, gadolinium, gallium, germanium, hafnium, holmium, iron (II and III), lanthanum, lithium, magnesium, manganese, neodymium, potassium, praseodymium, rubidium, samarium, silver, selenium, sodium, strontium, tellurium, terbium, thallium, thorium, tin, titanium, uranium, ytterbium, yttrium, zinc and zirconium. The pillared clay exhibits a basal d100 spacing of: (A) 9 to 18 angstroms; or (B) equal to or greater than about 18.5 angstroms. Use of the modified clays, with metallocene catalyst precursor components, provides active olefin polymerization catalysts, preferably in the substantial absence of aluminoxanes or boron-containing compounds.
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公开(公告)号：US10940460B2
公开(公告)日：2021-03-09
申请号：US15572675
申请日：2016-05-09
Applicant: W. R. Grace & Co.-Conn.
Inventor： Michael D. Jensen , John Robert McCauley , Andrew G. Singleton , Demetrius Michos
IPC: B01J21/16 , B01J23/10 , C08F4/6592 , B01J29/04 , C08F10/02
Abstract: An intercalated, modified and calcined smectite clay comprising (a) pillars comprising aluminum and: (i) at least one rare earth or lanthanide group metal; or (ii) at least one rare earth or lanthanide group metal and gallium; and (b) at least one ion-exchanged metal selected from the group consisting of aluminum, barium, beryllium, calcium, cerium, cesium, copper, chromium, gadolinium, gallium, germanium, hafnium, holmium, iron (II and III), lanthanum, lithium, magnesium, manganese, neodymium, potassium, praseodymium, rubidium, samarium, silver, selenium, sodium, strontium, tellurium, terbium, thallium, thorium, tin, titanium, uranium, ytterbium, yttrium, zinc and zirconium; wherein the clay is characterized by a basal d001 spacing equal to or greater than about 18.5 angstroms; and processes for making. The modified clays are suitably used as catalyst support-activators and when used in combination with metallocene catalyst precursor components, can provide active catalysts for polymerizing at least one olefin, preferably in the substantial absence of aluminoxanes or boron-containing compounds.
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3.发明申请公开(公告)号：US20180142047A1
公开(公告)日：2018-05-24
申请号：US15572658
申请日：2016-05-09
Applicant: W. R. Grace & Co.-Conn.
Inventor： Michael D. Jensen , John Robert McCauley , Andrew G. Singleton , Demetrius Michos
IPC: C08F10/02
CPC classification number: C08F10/02 , B01J31/00 , B01J31/143 , B01J31/1616 , B01J31/2295 , B01J2231/20 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C08F4/65925 , C08F4/65927 , C08F2410/01 , Y02P20/588 , C08F10/00 , C08F4/65916 , C08F4/65912 , C08F110/02 , C08F2500/12 , C08F210/16 , C08F210/14
Abstract: Catalyst support-activator for olefin polymerization catalysts, and processes for making, the support-activator comprising an intercalated, modified and calcined smectite clay comprising (a) pillars comprising aluminum and optionally: (i) at least one rare earth or lanthanide group metal; or (ii) at least one rare earth or lanthanide group metal and gallium; and (b) at least one ion-exchanged metal ion selected from the group consisting of aluminum, barium, beryllium, calcium, cerium, cesium, copper, chromium, gadolinium, gallium, germanium, hafnium, holmium, iron (II and III), lanthanum, lithium, magnesium, manganese, neodymium, potassium, praseodymium, rubidium, samarium, silver, selenium, sodium, strontium, tellurium, terbium, thallium, thorium, tin, titanium, uranium, ytterbium, yttrium, zinc and zirconium. The pillared clay exhibits a basal d100 spacing of: (A) 9 to 18 angstroms; or (B) equal to or greater than about 18.5 angstroms. Use of the modified clays, with metallocene catalyst precursor components, provides active olefin polymerization catalysts, preferably in the substantial absence of aluminoxanes or boron-containing compounds.
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4.发明申请公开(公告)号：US20160083587A1
公开(公告)日：2016-03-24
申请号：US14957884
申请日：2015-12-03
Applicant: W. R. Grace & Co-Conn.
Inventor： Demetrius Michos , Daniel Ray Fruge
CPC classification number: C09C3/063 , C01B33/18 , C01P2004/61 , C01P2004/62 , C08K3/22 , C08K3/36 , C08K9/02 , C09C1/3045 , C09C1/3054 , C09C1/3653 , C09C3/06 , C09D5/084 , C09D7/62 , C09D7/67 , C09D7/68 , C09D7/69 , Y10T428/2991
Abstract: Composite inorganic particles and compositions containing silica particles are disclosed. Methods of making silica particles and methods of using composite inorganic particles are also disclosed.
Abstract translation: 公开了含有二氧化硅颗粒的复合无机颗粒和组合物。 还公开了制备二氧化硅颗粒的方法和使用复合无机颗粒的方法。
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Patent Agency Ranking
公开(公告)号：US20180142048A1
公开(公告)日：2018-05-24
申请号：US15572675
申请日：2016-05-09
Applicant: W. R. Grace & Co.-Conn.
Inventor： Michael D. Jensen , John Robert McCauley , Andrew G. Singleton , Demetrius Michos
IPC: C08F10/02
CPC classification number: C08F10/02 , B01J21/16 , B01J23/10 , B01J29/049 , C08F4/65925 , C08F4/65927 , C08F2410/01 , C08F210/16 , C08F210/14 , C08F2500/12 , C08F110/02 , C08F10/00 , C08F4/65912 , C08F4/65916
Abstract: An intercalated, modified and calcined smectite clay comprising (a) pillars comprising aluminum and: (i) at least one rare earth or lanthanide group metal; or (ii) at least one rare earth or lanthanide group metal and gallium; and (b) at least one ion-exchanged metal selected from the group consisting of aluminum, barium, beryllium, calcium, cerium, cesium, copper, chromium, gadolinium, gallium, germanium, hafnium, holmium, iron (II and III), lanthanum, lithium, magnesium, manganese, neodymium, potassium, praseodymium, rubidium, samarium, silver, selenium, sodium, strontium, tellurium, terbium, thallium, thorium, tin, titanium, uranium, ytterbium, yttrium, zinc and zirconium; wherein the clay is characterized by a basal d001 spacing equal to or greater than about 18.5 angstroms; and processes for making. The modified clays are suitably used as catalyst support-activators and when used in combination with metallocene catalyst precursor components, can provide active catalysts for polymerizing at least one olefin, preferably in the substantial absence of aluminoxanes or boron-containing compounds.
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6.发明申请Improved Zeolite Particles For Adsorption and/or Desorption of Gases and Liquids 审中-公开改进的沸石颗粒吸附和/或解吸气体和液体公开(公告)号：US20170043318A1
公开(公告)日：2017-02-16
申请号：US15302413
申请日：2015-04-08
Applicant: W. R. Grace & Co.-Conn.
Inventor： James George Miller , Robert Harding , Demetrius Michos , James Neil Pryor
CPC classification number: B01J20/18 , A23L2/54 , A23L2/80 , A23V2002/00 , A61M16/107 , B01J20/103 , B01J20/183 , B01J20/28004 , B01J20/28011 , B01J20/28016 , B01J20/28019 , B01J20/2803 , B01J20/28071 , B01J20/3007 , B01J20/3028 , B01J20/3035 , B01J20/3042 , B01J20/3078 , B01J20/3092 , C01B32/50
Abstract: Disclosed are silica bound zeolite adsorbent particles which possess high volumetric gas adsorption capacity for the adsorption and/or desorption of gases. The adsorbent are highly effective as a gas source in volumetrically constrained applications. The silica-bound zeolite adsorbents possess a relatively high zeolite content simultaneously with a relatively low intra-particle pore volume as compared to the clay bound zeolite aggregates heretofore used as a gas source in volumetrically constrained environments, e.g. instant beverage carbonation processes, devices or systems.
Abstract translation: 公开了具有高气体吸附和/或解吸气体吸附能力的二氧化硅结合沸石吸附剂颗粒。 吸附剂在体积受限的应用中作为气体源是非常有效的。 与迄今用作体积受限环境中的气体源的粘土结合的沸石聚集体相比，具有二氧化硅结合的沸石吸附剂具有相对较高的沸石含量，同时具有相对较低的颗粒内孔体积。 即时饮料碳酸化工艺，设备或系统。
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公开(公告)号：US11643481B2
公开(公告)日：2023-05-09
申请号：US16966348
申请日：2019-02-01
Applicant: W. R. Grace & Co.-Conn.
Inventor： Amaia Montoya-Goni , John Kaarto , Michelle Ni Paine , Jose Manuel Rego , Feng Gu , Demetrius Michos , James Neil Pryor
IPC: C08F10/06 , C09D7/40 , C09D7/61 , C08J5/18 , C08K3/34 , C09D123/12 , C09D123/14 , C09J11/04 , C09J123/12 , C09J123/14 , C23F11/173
CPC classification number: C08F10/06 , C08J5/18 , C08K3/34 , C09D7/61 , C09D7/68 , C09D7/69 , C09D123/12 , C09D123/142 , C09J11/04 , C09J123/12 , C09J123/142 , C23F11/173 , C08J2323/12 , C08J2323/14 , C08K2003/343 , C08K2201/005
Abstract: The present invention provides polymer compositions having improved corrosivity, color stability and clarity. Also disclosed is a process of preparing the polymers. The process may comprise incorporating into the polymer an acid neutralizing amount of an amorphous aluminum silicate. The amorphous aluminum silicate may be present in the polymer in an amount such that the polymer composition having a Corrosivity Index of less than 6. A refractive index of the amorphous aluminum silicate may be the same or substantially the same as a refractive index of the polymer.
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公开(公告)号：US20200369798A1
公开(公告)日：2020-11-26
申请号：US16966348
申请日：2019-02-01
Applicant: W. R. Grace & Co.-Conn.
Inventor： Amaia Montoya-Goni , John Kaarto , Michelle Ni Paine , Jose Manuel Rego , Feng Gu , Demetrius Michos , James Neil Pryor
IPC: C08F10/06 , C08K3/34 , C08J5/18 , C09D123/12 , C09D123/14 , C09D7/61 , C09D7/40 , C09J123/12 , C09J123/14 , C09J11/04 , C23F11/173
Abstract: The present invention provides polymer compositions having improved corrosivity, color stability and clarity. Also disclosed is a process of preparing the polymers. The process may comprise incorporating into the polymer an acid neutralizing amount of an amorphous aluminum silicate. The amorphous aluminum silicate may be present in the polymer in an amount such that the polymer composition having a Corrosivity Index of less than 6. A refractive index of the amorphous aluminum silicate may be the same or substantially the same as a refractive index of the polymer.
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公开(公告)号：US10137428B2
公开(公告)日：2018-11-27
申请号：US15302413
申请日：2015-04-08
Applicant: W. R. Grace & Co.-Conn.
Inventor： James George Miller , Robert Harding , Demetrius Michos , James Neil Pryor
Abstract: Disclosed are silica bound zeolite adsorbent particles which possess high volumetric gas adsorption capacity for the adsorption and/or desorption of gases. The adsorbent are highly effective as a gas source in volumetrically constrained applications. The silica-bound zeolite adsorbents possess a relatively high zeolite content simultaneously with a relatively low intra-particle pore volume as compared to the clay bound zeolite aggregates heretofore used as a gas source in volumetrically constrained environments, e.g. instant beverage carbonation processes, devices or systems.
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