Herein is described a method of printing on a textile substrate. The method may comprise: a. applying a primer comprising a cross-linkable primer resin onto a surface of the textile substrate to form a primer layer; b. electrophotographically printing onto the primer layer an electrostatic ink composition comprising a cross-linkable thermoplastic resin to form a printed layer; c. applying a cross-linking composition comprising a cross-linking agent to the printed layer, wherein i. the cross-linking agent penetrates into at least the electrostatic ink composition and the primer layer; and/or ii. the cross-linking agent is a non-isocyanate agent; and d. activating the cross-linking agent. Printed textiles are also described.