A power storage device having flexibility is provided. A power storage device of which the capacity is not likely to deteriorate even when being curved is provided. A power storage device includes a first electrode, a second electrode, and an electrolytic solution. The first electrode and the second electrode overlap with each other. The first electrode includes a first current collector and a first active material layer. The first current collector has a first surface and a second surface. The first active material layer is provided on the first surface. The first current collector has a first bent portion with the second surface inside. The second surface includes a first region and a second region. The first region overlaps with the second region. The first region is connected to the second region at a portion different from the first bent portion.