Invention Grant
- Patent Title: Process for producing 1,3-butanediol and for optionally further producing (R)-3-hydroxybutyl (R)-3-hydroxybutyrate
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Application No.: US17008640Application Date: 2020-09-01
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Publication No.: US11078140B2Publication Date: 2021-08-03
- Inventor: Paul D. Bloom , Chi-Cheng Ma , Kevin J. Martin , Brennan Smith
- Applicant: Archer Daniels Midland Company
- Applicant Address: US IL Decatur
- Assignee: Archer Daniels Midland Company
- Current Assignee: Archer Daniels Midland Company
- Current Assignee Address: US IL Decatur
- Agent William B. Miller
- Main IPC: C07C29/149
- IPC: C07C29/149 ; B01J23/72 ; B01J25/00 ; C07C67/03 ; B01J25/02 ; C07C67/08

Abstract:
A process is described for producing 1,3-butanediol, wherein an ester of poly-(R)-3-hydroxybutyrate such as formed by transesterification with an alcohol is reduced by hydrogenation in the presence of a skeletal copper-based catalyst to provide 1,3-butanediol. The 1,3-butanediol may be transesterified by reaction with additional poly-(R)-3-hydroxybutyrate ester to produce (R)-3-hydroxybutyl (R)-3-hydroxybutyrate.
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