Embodiments of a User Equipment (UE) and methods for communication are generally described herein. The UE may be configured for carrier aggregation using a primary component carrier (CC) and a secondary CC. The UE may attempt to detect a sidelink synchronization signal (SLSS) from another UE on the primary CC. The UE may, if the SLSS from the other UE is detected: determine, based on the detected SLSS, a common time synchronization for the primary CC and the secondary CC for vehicle-to-vehicle (V2V) sidelink transmissions in accordance with the carrier aggregation. The UE may, if the SLSS from the other UE is not detected: transmit an SLSS to enable determination of the common time synchronization for the primary CC and the secondary CC by the other UE. The SLSS may be transmitted on the primary CC.