Invention Grant
- Patent Title: Transition metal bis(phenolate) complexes and their use as catalysts for olefin polymerization
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Application No.: US16787909Application Date: 2020-02-11
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Publication No.: US11254763B2Publication Date: 2022-02-22
- Inventor: Georgy P. Goryunov , Mikhail I. Sharikov , Vladislav A. Popov , Dmitry V. Uborsky , Alexander Z. Voskoboynikov , John R. Hagadorn , Michelle E. Titone , Alex E. Carpenter , Catherine A. Faler , Jo Ann M. Canich
- Applicant: ExxonMobil Chemical Patents Inc.
- Applicant Address: US TX Baytown
- Assignee: ExxonMobil Chemical Patents Inc.
- Current Assignee: ExxonMobil Chemical Patents Inc.
- Current Assignee Address: US TX Baytown
- Main IPC: C08F210/16
- IPC: C08F210/16 ; C08F10/02 ; C08F10/06 ; C08F110/06 ; C08F110/02 ; C07F7/00 ; B01J31/22 ; C08F4/64

Abstract:
This invention relates to transition metal complexes of a dianionic, tridentate ligand that features a central neutral heterocyclic Lewis base and two phenolate donors, where the tridentate ligand coordinates to the metal center to form two eight-membered rings. Preferably the bis(phenolate) complexes are represented by Formula (I): where M, L, X, m, n, E, E′, Q, R1, R2, R3, R4, R1′, R2′, R3′, R4′, A1, A1′, are as defined herein, where A1QA1′ are part of a heterocyclic Lewis base containing 4 to 40 non-hydrogen atoms that links A2 to A2′ via a 3-atom bridge with Q being the central atom of the 3-atom bridge.
Public/Granted literature
- US20200255553A1 Transition Metal Bis(Phenolate) Complexes and Their Use as Catalysts for Olefin Polymerization Public/Granted day:2020-08-13
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