Disclosed are a laser protective film and a laser protective device comprising the same. The laser protective film comprises, stackingly disposed: a first liquid crystal polymer layer for reflecting left-hand polarized light, a second liquid crystal polymer layer for reflecting right-hand polarized light, and a third liquid crystal polymer layer for absorbing incident laser. In the above way, the laser protective film of the present disclosure has a large angle of protection, high flexibility. In addition, it is easy to find any damage to the laser protective film of the present disclosure. Moreover, it can make modification to existing equipment. Thus, the present disclosure has a good application prospect in many fields such as laser goggles, window glass and the like.