An air-conditioning apparatus for a vehicle may include a radiator module; a refrigerant module; a hot portion for heat-exchanging with a condenser and a heater core of an internal air-conditioning module; a cold portion for heat-exchanging with an evaporator and a cooling core of the internal air-conditioning module; an electric portion for heat-exchanging with an electric component; a battery portion for heat-exchanging with a high-voltage battery; a connection module for connecting the hot portion, the electric portion, or the battery portion to any one or more radiators among a first radiator, a second radiator, and a third radiator; and a control unit configured of controlling the operations of a compressor and a valve.