Invention Grant
- Patent Title: Method for enhancing the adhesion of a layer for the protection of silver against tarnishing on a substrate comprising a silver surface
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Application No.: US16572203Application Date: 2019-09-16
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Publication No.: US11345993B2Publication Date: 2022-05-31
- Inventor: Christian Manasterski , Vladislav Spassov , Cedric Faure
- Applicant: The Swatch Group Research and Development Ltd
- Applicant Address: CH Marin
- Assignee: The Swatch Group Research and Development Ltd
- Current Assignee: The Swatch Group Research and Development Ltd
- Current Assignee Address: CH Marin
- Agency: Oblon, McClelland, Maier & Neustadt, L.L.P.
- Priority: EP18195859 20180921
- Main IPC: C23C16/06
- IPC: C23C16/06 ; C23C16/02 ; C23C16/40 ; C23C16/455 ; C23C16/56 ; G04B19/12 ; C22C5/08

Abstract:
A method is described for protecting a silver surface against tarnishing. This involves depositing a layer of a silver-copper alloy on a substrate, which may be a silver substrate. The alloy comprises between 0.1 wt % and 10 wt % of copper relative to the total weight of the alloy. At least one layer of a metal oxide or a nitride having a thickness in a range of 1 nm to 200 nm is deposited on the alloy to protect against tarnishing. The presence of copper in the silver-copper alloy enhances the alloy's adhesion without altering the silver color.
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