The invention provides, in the field of caring for and/or making up keratin materials, especially the skin, a composition in water-in-oil emulsion form, containing: a) a continuous oily phase, b) a discontinuous aqueous phase dispersed in the oily phase; c) at least baicalin and/or a derivative thereof and/or a plant extract containing the compound(s); d) at least one vitamin B3 and/or a derivative thereof; e) at least one xanthine base and/or a plant extract containing same; and f) at least one polyvalent cation salt.