A refrigerator includes an inner liner, an outer wrapper and a trim breaker that extends between the inner liner and the outer wrapper to define an insulated structural cabinet. The trim breaker includes a plurality of gas-blocking flakes, wherein each gas-blocking flake includes a longitudinal axis that extends substantially parallel with an elongated surface of the respective gas-blocking flake. The longitudinal axis and the elongated surface of each corresponding gas-blocking flake is oriented to be substantially parallel with a portion of an outer surface of the trim breaker located near the respective gas-blocking flake.