- 专利标题: MWW type zeolite, method for producing same, and cracking catalyst
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申请号: US16767011申请日: 2018-11-28
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公开(公告)号: US11447396B2公开(公告)日: 2022-09-20
- 发明人: Yoshihiro Kamimura , Akira Endou , Yasuo Yamazaki , Naonobu Katada , Satoshi Suganuma , Yoshihiro Kubota , Satoshi Inagaki
- 申请人: Mitsui Mining & Smelting Co., Ltd. , NATIONAL UNIVERSITY CORPORATION TOTTORI UNIVERSITY , NATIONAL UNIVERSITY CORPORATION YOKOHAMA NATIONAL UNIVERSITY
- 申请人地址: JP Tokyo; JP Tottori; JP Kanagawa
- 专利权人: Mitsui Mining & Smelting Co., Ltd.,NATIONAL UNIVERSITY CORPORATION TOTTORI UNIVERSITY,NATIONAL UNIVERSITY CORPORATION YOKOHAMA NATIONAL UNIVERSITY
- 当前专利权人: Mitsui Mining & Smelting Co., Ltd.,NATIONAL UNIVERSITY CORPORATION TOTTORI UNIVERSITY,NATIONAL UNIVERSITY CORPORATION YOKOHAMA NATIONAL UNIVERSITY
- 当前专利权人地址: JP Tokyo; JP Tottori; JP Kanagawa
- 代理机构: Rankin, Hill & Clark LLP
- 优先权: JPJP2017-227678 20171128
- 国际申请: PCT/JP2018/043866 WO 20181128
- 国际公布: WO2019/107448 WO 20190606
- 主分类号: C01B39/46
- IPC分类号: C01B39/46 ; C01B39/48 ; B01J29/70 ; B01J37/10 ; C07C4/18 ; B01J35/02
摘要:
Provided are the following: an MWW type zeolite which has many Brønsted acid sites when in the form of a proton type and which is highly suitable as a cracking catalyst for cumene; a method for producing same; and an application of same. The present invention provides an MWW type zeolite in which the ratio (B/A) of the peak intensity (B) attributable to tetracoordinate aluminum relative to the peak intensity (A) attributable to hexacoordinate aluminum is 2 or more in 27Al MAS NMR, when measured as an ammonium type. The present invention also provides a method for producing an MWW type zeolite, the method having a step for carrying out a hydrothermal synthesis reaction in the presence of: a seed crystal of an MWW type zeolite containing no organic structure-directing agent; and a reaction mixture containing a silica source, an alumina source, an alkali source, an organic structure-directing agent, and water. The reaction mixture satisfies the following molar ratio: X/SiO2
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