A honeycomb body having a porous ceramic honeycomb structure with a first end, a second end, and a plurality of walls having wall surfaces defining a plurality of inner channels. A highly porous layer is disposed on one or more of the wall surfaces of the honeycomb body. The highly porous layer has a porosity greater than 90%, and has an average thickness of greater than or equal to 0.5 μm and less than or equal to 10 μm. A method of making a honeycomb body includes depositing a layer precursor on a ceramic honeycomb body and binding the layer precursor to the ceramic honeycomb body to form the highly porous layer.