A power supply structure and an electronic cigarette having same are provided. The power supply structure includes at least two rechargeable batteries connected in series, a charging circuit connected to the rechargeable batteries and used to charge the rechargeable batteries, and a switching circuit connected to the at least two rechargeable batteries. The switching circuit is used to switch the at least two rechargeable batteries into battery series circuits having different number of rechargeable batteries connected in series. The charging circuit is used to detect the voltages of the battery series circuits and convert a standard charging voltage into different charging voltages for charging the battery series circuits according to the detected voltages.