Provided is a relay goods picking system, the system includes: a plurality of carrying robots, a manual picking area, auxiliary pickup tools for manual goods picking which store goods for manual picking, a robot picking inventory container area provided with a plurality of inventory containers used for storing goods and being carried by the plurality of carrying robots, operating positions and a control system capable of communicating with the plurality of carrying robots and manual picking persons. For a mixed order which involves both goods in the manual picking area and goods in the robot picking rack area, under control of the control system, a person-to-goods picking mode and a goods-to-person picking mode are used to complete the goods picking.