A method of controlling a power converter is provided. The power converter generates a three-phase output power by switching an input power through a plurality of switches. The method includes steps of: acquiring a three-phase output command corresponding to the three-phase output power; comparing the three-phase output command with a control carrier to acquire a voltage phase angle corresponding to the three-phase output command; acquiring a three-phase current value of the three-phase output power; detecting the voltage phase angle and a positive/negative change of the three-phase current value to decide a zero-sequence voltage; composing the zero-sequence voltage and the three-phase output command to acquire a three-phase output expected value; comparing the three-phase expected values with the control carrier to acquire a turned-on time of each switch; and switching the input power to adjust the three-phase output power according to the turned-on time of each switch.