Nonaqueous electrolyte secondary battery
Abstract:
Provided is a nonaqueous electrolyte secondary battery with a positive electrode active material that contains an excess of Li and has a layered structure, the nonaqueous electrolyte secondary battery having a high output and enabling prevention of gelation of the positive electrode active material layer-forming paste during production. The herein disclosed nonaqueous electrolyte secondary battery includes a positive electrode, a negative electrode, and a nonaqueous electrolyte. The positive electrode includes a positive electrode active material layer. The positive electrode active material layer contains a lithium composite oxide having a layered structure as a positive electrode active material. The compositional ratio of the lithium atom to the metal atom other than a lithium atom contained in the lithium composite oxide is greater than 1. The lithium composite oxide is in the form of porous particles. Each of the porous particles has at least two voids each of which has the percentage of a void area with respect to the area occupied by each of the particles in a cross-sectional view thereof of at least 1%. Each of the porous particles is provided with a coating of lithium tungstate on a surface thereof.
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