- 专利标题: Method for preparing block copolymer hollow fiber membrane by melt spinning-stretching and selective swelling
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申请号: US18001092申请日: 2022-03-23
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公开(公告)号: US11766640B2公开(公告)日: 2023-09-26
- 发明人: Yong Wang , Dinglei Zhong , Jiemei Zhou
- 申请人: NANJING TECH UNIVERSITY
- 申请人地址: CN Jiangsu
- 专利权人: NANJING TECH UNIVERSITY
- 当前专利权人: NANJING TECH UNIVERSITY
- 当前专利权人地址: CN Jiangsu
- 代理机构: HAMRE, SCHUMANN, MUELLER & LARSON, P.C.
- 优先权: CN 2110313177.7 2021.03.24
- 国际申请: PCT/CN2022/082365 2022.03.23
- 国际公布: WO2022/199592A 2022.09.29
- 进入国家日期: 2022-12-08
- 主分类号: B01D67/00
- IPC分类号: B01D67/00 ; B01D71/52 ; B01D69/08 ; B01D71/68 ; B01D71/80 ; D01D5/24 ; D01F1/08
摘要:
The disclosure provides a method for preparing a hollow fiber membrane by melt spinning-stretching and selective swelling, including: preparing a nascent hollow fiber by melt spinning in an inert gas protective atmosphere by using an amphiphilic block copolymer as a film forming material, and stretching the nascent hollow fiber in the cooling process, a stretch rate being controlled at 200-540 mm/min, and a stretch ratio being controlled at 150-600%; immersing the obtained hollow fiber in a swelling solvent, and treating the hollow fiber in a water bath at 65° C. for 1 h; and then transferring the hollow fiber into a long-chain alkane solvent, treating the hollow fiber at the same temperature for 1-12 h, and after the completion of the treatment, immediately taking out the hollow fiber and drying the hollow fiber to obtain the hollow fiber membrane with a bicontinuous porous structure. By combining the melt spinning-stretching and the selective swelling, the method of the disclosure can synchronously and continuously improve the permeability and selectivity of the hollow fiber membrane. The treatment in the long-chain alkane solvent can make the polar chain excessively enriched on the surface of the membrane migrate inward, thereby improving the performance of the hollow fiber membrane.
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