- 专利标题: Flame-retardant and color-stable polyamide molding compounds
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申请号: US16756210申请日: 2018-10-09
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公开(公告)号: US11859084B2公开(公告)日: 2024-01-02
- 发明人: Sebastian Hörold , Elke Schlosser , Eva-Maria Leuschner
- 申请人: CLARIANT INTERNATIONAL LTD
- 申请人地址: CH Muttenz
- 专利权人: CLARIANT INTERNATIONAL LTD
- 当前专利权人: CLARIANT INTERNATIONAL LTD
- 当前专利权人地址: CH Muttenz
- 代理商 Natali Richter
- 优先权: DE 2017218453.1 2017.10.16
- 国际申请: PCT/EP2018/077483 2018.10.09
- 国际公布: WO2019/076688A 2019.04.25
- 进入国家日期: 2020-04-15
- 主分类号: C08L77/06
- IPC分类号: C08L77/06
摘要:
The invention relates to a flame-retardant polyamide composition containing: as component A) 1 to 96 wt. % of one or more thermoplastic polyamides; as component B) 2 to 25 wt. % of a diorganylphosphinic acid salt of formula (I),
wherein R1 and R2 are the same or different and C1-C18 alkyl is linear, branched or cyclical, C6-C18 aryl, C7-C18 arylalkyl and/or C7-C18 alkylaryl; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is 1 to 4; n is 1 to 4; as component C) 2 to 20 wt. % of at least a further polymer component, selected from the classes of thermoplastic polyester and polyester elastomers; as component D) 0 to 20 wt. % of a salt of the phosphorous acid of general formula (II),
[HP(═O)O2]2−Mm+ (II)
in which M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na and/or K; as component E) 0 to 20 wt. % of one or more condensation products of melamine and/or reaction products of melamine with phosphoric acids and/or melamine cyanurate; as component F) 0 to 50 wt. % of a filler and/or reinforcing agent; as component G) 0 to 5 wt. % of a compatibilizing agent for the polymer components; as component H) 0 to 2 wt. % of a phosphite or phosphonite or mixtures thereof; and as component I) 0 to 2 wt. % of an ester or salt of long-chained aliphatic carboxylic acids (fatty acids) which typically have chain lengths of C14 to C40, wherein the sum of the components always amounts to 100 wt. %.
wherein R1 and R2 are the same or different and C1-C18 alkyl is linear, branched or cyclical, C6-C18 aryl, C7-C18 arylalkyl and/or C7-C18 alkylaryl; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is 1 to 4; n is 1 to 4; as component C) 2 to 20 wt. % of at least a further polymer component, selected from the classes of thermoplastic polyester and polyester elastomers; as component D) 0 to 20 wt. % of a salt of the phosphorous acid of general formula (II),
[HP(═O)O2]2−Mm+ (II)
in which M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na and/or K; as component E) 0 to 20 wt. % of one or more condensation products of melamine and/or reaction products of melamine with phosphoric acids and/or melamine cyanurate; as component F) 0 to 50 wt. % of a filler and/or reinforcing agent; as component G) 0 to 5 wt. % of a compatibilizing agent for the polymer components; as component H) 0 to 2 wt. % of a phosphite or phosphonite or mixtures thereof; and as component I) 0 to 2 wt. % of an ester or salt of long-chained aliphatic carboxylic acids (fatty acids) which typically have chain lengths of C14 to C40, wherein the sum of the components always amounts to 100 wt. %.
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