- 专利标题: Method for producing 2,5-furandicarboxylic acid (FDCA) by electrocatalytic oxidation of 5-hydroxymethylfurfural (HMF) and simultaneously generating hydrogen by water electrolysis
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申请号: US17762116申请日: 2020-06-10
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公开(公告)号: US11859296B2公开(公告)日: 2024-01-02
- 发明人: Chunlin Chen , Zhenqiang Zhou , Jian Zhang
- 申请人: NINGBO INSTITUTE OF MATERIALS TECHNOLOGY & ENGINEERING, CHINESE ACADEMY OF SCIENCES
- 申请人地址: CN Ningbo
- 专利权人: NINGBO INSTITUTE OF MATERIALS TECHNOLOGY & ENGINEERING, CHINESE ACADEMY OF SCIENCES
- 当前专利权人: NINGBO INSTITUTE OF MATERIALS TECHNOLOGY & ENGINEERING, CHINESE ACADEMY OF SCIENCES
- 当前专利权人地址: CN Ningbo
- 代理机构: Bayramoglu Law Offices LLC
- 优先权: CN 1910891734.6 2019.09.20
- 国际申请: PCT/CN2020/095323 2020.06.10
- 国际公布: WO2021/051897A 2021.03.25
- 进入国家日期: 2022-03-21
- 主分类号: C25B3/05
- IPC分类号: C25B3/05 ; C25B3/23 ; C25B11/067 ; C25B11/077 ; C25B11/061 ; C25B3/07 ; C25B11/065 ; C25B11/054 ; C25B9/17 ; C25B11/091 ; C07D307/68 ; C25B1/04
摘要:
A method for producing 2,5-furandicarboxylic acid (FDCA) by electrocatalytic oxidation of 5-hydroxymethylfurfural (HMF) is provided, where the catalytic oxidation is conducted using an electrolytic cell; the electrolytic cell is a three-electrode electrolytic cell or a two-electrode electrolytic cell; an anode used is a monolithic electrode; the monolithic electrode includes a carrier and a catalytically active substance loaded on the carrier; and the catalytically active substance includes cobaltosic oxide particle-encapsulated nitrogen-doped carbon nanowires. The method has high activity and high selectivity, and the anodic catalyst is highly tolerant to HMF.
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