The invention relates to a semiconductive polymer composition comprising a polymer component, a conducting component and a crosslinking agent, wherein the polymer component comprises a polar polyethylene and the crosslinking agent comprises an aliphatic mono- or bifunctional peroxide or, alternatively, a monofunctional peroxide containing an aromatic group, and the crosslinking agent is present in an amount which is Z wt %, based on the total amount (100 wt %) of the polymer composition, and Z1≤Z≤Z2, wherein Z1 is 0.01 and Z2 is 5.0, an article being e.g. a cable, e.g. a power cable, and processes for producing a semiconductive polymer composition and an article; useful in different end applications, such as wire and cable (W&C) applications.