- 专利标题: Oxidation of 5-hydroxy-2-furanone to maleates
-
申请号: US17414419申请日: 2019-12-20
-
公开(公告)号: US11912656B2公开(公告)日: 2024-02-27
- 发明人: Marc Crockatt , Roman Latsuzbaia , Johan Urbanus , Earl Lawrence Vincent Goetheer , Richard Antonius Van Heck
- 申请人: Nederlandse Organisatie voor toegepast-natuurwetenschappelijk onderzoek TNO
- 申请人地址: NL 's-Gravenhage
- 专利权人: Nederlandse Organisatie voor toegepast-natuurwetenschappelijk onderzoek TNO
- 当前专利权人: Nederlandse Organisatie voor toegepast-natuurwetenschappelijk onderzoek TNO
- 当前专利权人地址: NL 's-Gravenhage
- 代理机构: Banner & Witcoff, Ltd.
- 优先权: WO TNL2018050881 2018.12.21
- 国际申请: PCT/NL2019/050867 2019.12.20
- 国际公布: WO2020/130832A 2020.06.25
- 进入国家日期: 2021-06-16
- 主分类号: C07C51/21
- IPC分类号: C07C51/21 ; C07C51/29 ; C07C51/305 ; C25B3/07 ; C25B3/23 ; C07C51/235 ; C25B11/04 ; C25B11/052 ; C25B11/042
摘要:
The invention is directed to a process for preparing maleic acid or a derivative thereof, the process comprising a step b) of oxidizing 5-hydroxy-2(5H)-furanone and/or cis-β-formylacrylic acid to maleic acid or a derivative thereof by contacting the 5-hydroxy-2(5H)-furanone and/or cis-β-formylacrylic acid with molecular oxygen (O2) in the presence of a catalyst. In a particular embodiment, the step b) is preceded by a step a) of oxidizing a furanic compound according to formula I into the 5-hydroxy-2(5H)-furanone and/or cis-β-formylacrylic acid,
wherein R1 is H, CH2OH, CO2H or CHO and R2 is H, OH, C1-C6 alkyl or O(C1-C6 alkyl), or esters, ethers, amides, acid halides, anhydrides, carboximidates, nitriles, and salts of formula I.
wherein R1 is H, CH2OH, CO2H or CHO and R2 is H, OH, C1-C6 alkyl or O(C1-C6 alkyl), or esters, ethers, amides, acid halides, anhydrides, carboximidates, nitriles, and salts of formula I.
公开/授权文献
- US20220090274A1 Oxidation of 5-Hydroxy-2-Furanone to Maleates 公开/授权日:2022-03-24
信息查询