Invention Grant
- Patent Title: Copolyesters of 2,4-FDCA with increased crystallization control
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Application No.: US17586535Application Date: 2022-01-27
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Publication No.: US12018119B2Publication Date: 2024-06-25
- Inventor: Felipe Cicaroni Fernandes , Iuri Estrada Gouvea , Bárbara Mano
- Applicant: Braskem S.A.
- Applicant Address: BR Camacari-BA
- Assignee: BRASKEM S.A.
- Current Assignee: BRASKEM S.A.
- Current Assignee Address: BR Camacari
- Agency: Morgan, Lewis & Bockius LLP
- Main IPC: C08G63/40
- IPC: C08G63/40 ; C08G63/183

Abstract:
The present disclosure provides a copolyester including a dicarboxylic acid component A comprising a terephthalic acid residue or ester-forming derivative thereof, or a mixture thereof, and a 2,4-furandicarboxylic acid residue or ester-forming derivative thereof, or a mixture thereof, and a diol component B comprising an alkanediol residue having from 2 to 22 carbon atoms, wherein the dicarboxylic acid component A has a total molar content, and wherein the 2,4-furandicarboxylic acid residue or ester-forming derivative thereof, is present in an amount of from 0.1 to 10 mol %, with respect to the total molar content of the dicarboxylic acid component A. Inventive copolyesters have a slower crystallization rate, a higher gas barrier to CO2 and O2 and a higher ratio of 14C to 12C as measured by ASTM D6866 when compared to a comparable copolyester comprising isophthalic acid instead of 2,4-furandicarboxylic acid.
Public/Granted literature
- US20220243006A1 COPOLYESTERS OF 2,4-FDCA WITH INCREASED CRYSTALLIZATION CONTROL Public/Granted day:2022-08-04
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