A layered structure for a fuel cell comprises a carbon-based catalyst-free gas diffusion layer substrate and a carbon-based microporous layer, which is joined to the gas diffusion layer substrate and comprises a plurality of carbon carriers or carbon fibers embedded into an ion-conducting polymer binder mixture. The polymer binder mixture comprises a sulfur-free binding polymer and a sulfonated polymer, and a fraction of the binding polymer at or near a surface of the microporous layer facing away from the gas diffusion layer substrate is less than or equal to a fraction of the sulfonated polymer. A method for producing a layered structure of this type is also provided.