发明申请
- 专利标题: Stable and selective dehydrogenation catalyst and a process for the preparation thereof
- 专利标题(中): 稳定和选择性脱氢催化剂及其制备方法
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申请号: US09832187申请日: 2001-04-10
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公开(公告)号: US20020022755A1公开(公告)日: 2002-02-21
- 发明人: Rajeswer Dongara , Krishnamurthy Konda Ramaswamy
- 申请人: INDIAN PETROCHEMICALS CORPORATIONLIMITED
- 申请人地址: null
- 专利权人: INDIAN PETROCHEMICALS CORPORATIONLIMITED
- 当前专利权人: INDIAN PETROCHEMICALS CORPORATIONLIMITED
- 当前专利权人地址: null
- 优先权: IN375/MUM/2000 20000420
- 主分类号: C07C005/333
- IPC分类号: C07C005/333 ; B01J027/125 ; B01J027/13 ; B01J027/128 ; B01J027/135 ; B01J027/138 ; B01J027/06
摘要:
A novel catalyst for use in dehydrogenation of saturated hydrocarbons to unsaturated hydrocarbons and a method for its preparation is disclosed. Said catalyst comprises a composite incorporated within its spatial geometry on a percentage by weight basis, with a uniform concentration gradient, the following active elements: from 0.1 to 5.0% of a noble metal; from 0.1 to 5.0% of a metal of Group IV A; from 0.1 to 6.0% of a metal Group III A; from 0.1 to 10.0% of an alkali or alkaline earth metal element; from 0.01 to 10.0% of a halogen; and from 0.1 to 5.0% of a metal Group VIII selected from Fe, Co and Ni provided on a high surface area meso or macroporous support. The the high surface mesoporous support comprises a spheroidal gamma alumina support with a diameter of 1.4 to 2.0 mm, a surface area in the range of from 150 to 220 m2/g, with bimodal narrow pore size distribution, water adsorption capacity in the range of from 1.4 to 2.5 ml/g, gamma crystallinity in the range of 60 to 80% and a bulk density in the range of 0.25 to 0.4 g/ml.
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