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    Stable and selective dehydrogenation catalyst and a process for the preparation thereof
    1.
    发明申请
    Stable and selective dehydrogenation catalyst and a process for the preparation thereof 失效
    稳定和选择性脱氢催化剂及其制备方法

    公开(公告)号：US20020022755A1

    公开(公告)日：2002-02-21

    申请号：US09832187

    申请日：2001-04-10

    Applicant: INDIAN PETROCHEMICALS CORPORATIONLIMITED

    Inventor： Rajeswer Dongara ,  Krishnamurthy Konda Ramaswamy

    IPC: C07C005/333 ,  B01J027/125 ,  B01J027/13 ,  B01J027/128 ,  B01J027/135 ,  B01J027/138 ,  B01J027/06

    CPC classification number: C07C5/417 ,  B01J23/8966 ,  B01J27/13 ,  C07C5/325 ,  C07C5/3337 ,  C07C2523/02 ,  C07C2523/04 ,  C07C2523/08 ,  C07C2523/10 ,  C07C2523/14 ,  C07C2523/56 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/755 ,  C07C2523/89 ,  C07C2527/06

    Abstract: A novel catalyst for use in dehydrogenation of saturated hydrocarbons to unsaturated hydrocarbons and a method for its preparation is disclosed. Said catalyst comprises a composite incorporated within its spatial geometry on a percentage by weight basis, with a uniform concentration gradient, the following active elements: from 0.1 to 5.0% of a noble metal; from 0.1 to 5.0% of a metal of Group IV A; from 0.1 to 6.0% of a metal Group III A; from 0.1 to 10.0% of an alkali or alkaline earth metal element; from 0.01 to 10.0% of a halogen; and from 0.1 to 5.0% of a metal Group VIII selected from Fe, Co and Ni provided on a high surface area meso or macroporous support. The the high surface mesoporous support comprises a spheroidal gamma alumina support with a diameter of 1.4 to 2.0 mm, a surface area in the range of from 150 to 220 m2/g, with bimodal narrow pore size distribution, water adsorption capacity in the range of from 1.4 to 2.5 ml/g, gamma crystallinity in the range of 60 to 80% and a bulk density in the range of 0.25 to 0.4 g/ml.

    Abstract translation: 公开了一种用于将饱和烃脱氢成不饱和烃的新型催化剂及其制备方法。 所述催化剂包含在其空间几何形状内基于重量百分数掺入的具有均匀浓度梯度的复合材料，以下活性元素：0.1-5.0％的贵金属; 0.1至5.0％的IVA族金属; 0.1〜6.0％的金属IIIA族; 0.1至10.0％的碱金属或碱土金属元素; 0.01〜10.0％的卤素; 和0.1〜5.0％的选自Fe，Co和Ni的金属VIII族，提供在高表面积的中等或大孔载体上。 高表面介孔载体包括直径为1.4至2.0mm的球形γ氧化铝载体，表面积为150-220m2 / g，双峰窄孔径分布，水吸附容量范围为 从1.4至2.5ml / g，γ结晶度在60至80％范围内，堆积密度在0.25至0.4g / ml的范围内。

    Components and catalysts for the (co) polymerization of olefins
    3.
    发明申请
    Components and catalysts for the (co) polymerization of olefins 有权
    用于（共）烯烃聚合的组分和催化剂

    公开(公告)号：US20020010081A1

    公开(公告)日：2002-01-24

    申请号：US09732523

    申请日：2000-12-06

    Inventor： Zhulan Li ,  Juxiu Yang ,  Mingzhi Gao ,  Yun Zhao ,  Bingquan Mao ,  Aichun Yang ,  Chunmin Ding ,  Wenbo Song ,  Kunzheng Liu

    IPC: B01J031/00 ,  B01J027/138 ,  B01J037/00 ,  C08F004/02 ,  C08F004/60

    CPC classification number: C08F10/00 ,  C08F4/654

    Abstract: The present invention relates to a catalyst component for the (co)polymerization of olefins comprising titanium, magnesium, halogen and a mixed electron-donor and a catalyst for the (co)polymerization of olefins comprisin: (A) the catalyst component; (B) an organic aluminum compound; and (C) an organic silicon compound. The polymer with high and adjustable stereospecificity and broad molecular weight distribution can be prepared by using the catalyst.

    Abstract translation: 本发明涉及包含钛，镁，卤素和混合电子给体的烯烃（共）聚合的催化剂组分和用于烯烃（共））聚合的催化剂，其包括：（A）催化剂组分; （B）有机铝化合物; 和（C）有机硅化合物。 可以通过使用催化剂制备具有高和可调立体定向性和宽分子量分布的聚合物。

    Selective hydrogenation catalyst and processes therefor and therewith
    4.
    发明申请
    Selective hydrogenation catalyst and processes therefor and therewith 失效
    选择性氢化催化剂及其工艺

    公开(公告)号：US20040248732A1

    公开(公告)日：2004-12-09

    申请号：US10260018

    申请日：2002-12-10

    Applicant: Phillips Petroleum Company

    Inventor： Tin-Tack Peter Cheung

    IPC: B01J023/58 ,  B01J027/06 ,  B01J027/125 ,  B01J027/138 ,  B01J027/135 ,  B01J027/14 ,  B01J027/13

    CPC classification number: B01J27/12 ,  B01J23/50 ,  B01J23/66 ,  C07C7/167 ,  C07C2527/12 ,  Y02P20/52 ,  C07C11/04

    Abstract: A catalyst composition comprising an inorganic support material, a palladium component, a silver component, and a promotor component having the formula XYFn, wherein X is an alkaline metal, Y is an element selected from the group consisting of antimony, phosphorus, boron, aluminum, gallium, indium, thallium, and arsenic, and n is an integer which makes YFn a monovalent anion. The above-described catalyst is employed as a catalyst in the selective hydrogenation of acetylene. The above-described catalyst is made by incorporating a palladium component, a silver component, and a promotor component into an inorganic support material.

    Abstract translation: 一种催化剂组合物，其包含无机载体材料，钯组分，银组分和具有式XYFn的促进剂组分，其中X是碱金属，Y是选自锑，磷，硼，铝的元素 ，镓，铟，铊和砷，n为使YFn为一价阴离子的整数。 上述催化剂用作乙炔的选择性氢化中的催化剂。 上述催化剂是通过将钯组分，银组分和促进剂组分并入无机载体材料中制成的。

    Process and catalyst for the preparation of acetylpyridines
    5.
    发明申请
    Process and catalyst for the preparation of acetylpyridines 失效
    用于制备乙酰吡啶的方法和催化剂

    公开(公告)号：US20040073040A1

    公开(公告)日：2004-04-15

    申请号：US10467381

    申请日：2003-08-07

    Inventor： Roderick John Chuck

    IPC: B01J027/135 ,  B01J027/138 ,  B01J027/06 ,  C07D213/46

    CPC classification number: B01J21/063 ,  B01J23/02 ,  B01J23/04 ,  B01J35/10 ,  B01J35/1014 ,  B01J35/1042 ,  C07D213/50

    Abstract: A process for the production of acetylopyridines of the formula (1): 1 by reacting a pyridinecarboxylic ester of the formula (II): 2 wherein R1 is C1-8-alkyl, with acetic acid in the gas phase in the presence of a catalyst. The active material of the catalyst is titanium dioxide and at least one alkali or alkaline earth metal oxide, and it is supported on an alumina-silica support having an apparent porosity of at least 50 percent. The process has the advantage of producing only small amounts of by-products (e.g, pyidine).

    Abstract translation: 制备式（1）的乙酰吡啶的方法：通过使式（II）的吡啶羧酸酯与其中R 1为C 1-8 - 烷基的乙酸在气相中在 催化剂。 催化剂的活性材料是二氧化钛和至少一种碱金属或碱土金属氧化物，并且其负载在表观孔隙率至少为50％的氧化铝 - 二氧化硅载体上。 该方法具有仅产生少量副产物（例如吡啶）的优点。

    Production of Ziegler-Natta catalysts
    7.
    发明申请
    Production of Ziegler-Natta catalysts 失效
    齐格勒 - 纳塔催化剂的生产

    公开(公告)号：US20010016553A1

    公开(公告)日：2001-08-23

    申请号：US09760681

    申请日：2001-01-16

    Applicant: Fina Research, S.A., a corporation of the Country of Belgium

    Inventor： Guy Debras ,  Christian Lamotte

    IPC: B01J027/138

    CPC classification number: C08F10/00 ,  C08F4/6565 ,  C08F4/654

    Abstract: A process for producing a Ziegler-Natta catalyst, the process comprising reacting an organo magnesium compound with a halogenated compound to produce crystalline magnesium halide having an intense diffraction line in an x-ray spectrum thereof at lattice distance within the range of from 2.56 to 3.20 Angstroms and titanating the magnesium halide by mixing the magnesium halide with a titanium compound whereby the titanated magnesium halide hasp in an x-ray spectrum thereof, a halo appearing at a lattice distance within the range from 2.56 to 3.30 Angstroms.

    Abstract translation: 一种齐格勒 - 纳塔催化剂的制备方法，该方法包括使有机镁化合物与卤代化合物反应，以产生在x射线谱中具有强衍射线的晶格卤化镁，晶格卤化镁的晶格距离在2.56至3.20范围内 通过将卤化镁与钛化合物混合，从而钛化镁卤化物在其X射线光谱中，卤素以2.56至3.30埃的晶格距离出现，从而对卤化镁进行钛化处理。

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