- 专利标题: Olefin oligomerization catalysts, their production and use
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申请号: US10300110申请日: 2002-11-19
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公开(公告)号: US20030105250A1公开(公告)日: 2003-06-05
- 发明人: Gregory T. Whiteker
- 主分类号: C08F004/06
- IPC分类号: C08F004/06 ; C08F004/44 ; C08F004/72
摘要:
This invention relates to a method to oligomerize ethylene comprising combining ethylene with a catalyst system comprising an activator and one or more phenoxide group metal compounds represented by the formula: 1 wherein R3, R4, R5, R8, R9 and R10 may each independently be hydrogen, a halogen, a heteroatom containing group or a C1 to C100 group, provided that at least one of these groups has a Hammett nullp value (Hansch, et al Chem. Rev. 1991, 91, 165) greater than 0.20; R2 and R7 may each independently be alkyl, aryl or silyl groups; R1 and R6 may each independently be an alkyl group, an aryl group, an alkoxy group, or an amino group; N is nitrogen; H is hydrogen; O is oxygen; M is a group 4 transition metal; and each X may each independently be an anionic ligand or a dianionic ligand.
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