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    Processes for producing cycloolefin addition polymer
    2.
    发明申请
    Processes for producing cycloolefin addition polymer 有权
    生产环烯加成聚合物的方法

    公开(公告)号：US20040063873A1

    公开(公告)日：2004-04-01

    申请号：US10466429

    申请日：2003-07-16

    发明人： Kenzo Ohkita ,  Noboru Oshima ,  Takashi Imamura ,  Takashi Tsubouchi

    IPC分类号： C08F004/06

    CPC分类号： C08F32/00 ,  Y10S526/903

    摘要： A cyclic olefin having a specific polar group is polymerized by addition polymerization in a hydrocarbon solvent, using a polymerization catalyst component containing (i) a specific transition metal compound, (ii) a Lewis acid compound and (iii) an alkyl aluminoxane, or the cyclic olefin is polymerized by addition polymerization in the hydrocarbon solvent, using the polymerization catalyst component, by further adding at least one aromatic vinyl compound and at least one cyclic nonconjugated polyene compound, or either one of them as a molecular weight modifier, thereby obtaining a cyclic olefinic addition polymer.

    摘要翻译： 使用含有（i）特定的过渡金属化合物，（ii）路易斯酸化合物和（iii）烷基铝氧烷的聚合催化剂组分的聚合催化剂组分，通过在烃溶剂中进行加成聚合来聚合具有特定极性基团的环状烯烃，或 通过进一步添加至少一种芳族乙烯基化合物和至少一种环状非共轭多烯化合物或其中任一种作为分子量调节剂，通过在烃溶剂中的加成聚合使用聚合催化剂组分使环烯烃聚合，得到 环烯烃加成聚合物。

    Polymerisation initiator and use
    3.
    发明申请
    Polymerisation initiator and use 失效
    聚合引发剂和用途

    公开(公告)号：US20040044156A1

    公开(公告)日：2004-03-04

    申请号：US10276266

    申请日：2003-08-28

    发明人： David Mark Haddleton

    IPC分类号： C08F004/06 ,  B01J031/00

    CPC分类号： C08F4/00 ,  C08F4/027 ,  C08F4/06 ,  C08F4/10 ,  C08F4/44 ,  C08F4/50 ,  C08F293/005 ,  C08F2438/01

    摘要： The application discloses supported initiators for transition metal medicated living free radical and/or atom transfer polymerisation comprising an initiator moiety attached to a support via a selectively cleavable link, and their use to produce polymers.

    摘要翻译： 本申请公开了用于过渡金属药物活性自由基和/或原子转移聚合的负载引发剂，其包含通过可选择性切割链接连接到载体上的引发剂部分及其用于生产聚合物的用途。

    (Meth) acrylic acid (salt) polymer and its production process
    6.
    发明申请
    (Meth) acrylic acid (salt) polymer and its production process 失效
    （Meth）丙烯酸（盐）聚合物及其生产工艺

    公开(公告)号：US20030149206A1

    公开(公告)日：2003-08-07

    申请号：US10281971

    申请日：2002-10-29

    发明人： Takashi Tomita ,  Tsutomu Yuasa ,  Hirokatsu Kawakami

    IPC分类号： C08F004/06 ,  C08F004/28

    CPC分类号： C08F290/061 ,  C04B24/2647 ,  C04B2103/408 ,  C08F220/04 ,  C08F220/28 ,  C08F290/06 ,  C08F290/062

    摘要： There is provided: a (meth)acrylic acid (salt) polymer which has high properties and is little colored; and a process which can produce this polymer with a high polymerization conversion without causing the corrosion of the reaction vessel. When a (meth)acrylic acid (salt) polymer is obtained by carrying out polymerization of an unsaturated monocarboxylic monomer (a) and an unsaturated polyalkylene glycolic monomer (b) with a polymerization initiator, either a redox polymerization initiator including hydrogen peroxide and a reducing agent is used as the polymerization initiator in a specific amount, or the unsaturated polyalkylene glycolic monomer is subjected to the polymerization in the form of an esterification reaction product as obtained by a process including the steps of: esterifying the unsaturated monocarboxylic monomer and a polyalkylene glycol in a specific charging ratio in the presence of an acid catalyst in a manner for a portion of the residual unsaturated monocarboxylic monomer as a starting raw material to remain; and then neutralizing the acid catalyst and the residual unsaturated monocarboxylic monomer (a) with a basic substance after the esterification; and the polymerization is carried out under conditions where the pH during the polymerization is in the range of 3.2 to 7.0.

    摘要翻译： 提供：具有高性能并且着色少的（甲基）丙烯酸（盐）聚合物; 以及可以在不引起反应容器的腐蚀的情况下以高聚合转化率生产该聚合物的方法。 当通过用聚合引发剂进行不饱和单羧酸单体（a）和不饱和聚亚烷基二醇单体（b）的聚合获得（甲基）丙烯酸（盐））聚合物时，可以使用包含过氧化氢的还原性氧化还原聚合引发剂 作为聚合引发剂使用，或不饱和聚亚烷基二醇单体以酯化反应产物的形式进行聚合，所述酯化反应产物通过包括以下步骤的方法得到：不饱和单羧酸单体和聚亚烷基二醇的酯化 在酸催化剂存在下，以残留不饱和单羧酸单体的一部分作为起始原料保留的方式，以特定的带电比例; 然后在酯化后用碱性物质中和酸催化剂和残余不饱和单羧酸单体（a）; 聚合反应在聚合反应中的pH在3.2〜7.0的条件下进行。

    Method for the production of a catalyst system for the polymerisation of olefins
    9.
    发明申请
    Method for the production of a catalyst system for the polymerisation of olefins 有权
    制备烯烃聚合催化剂体系的方法

    公开(公告)号：US20030045660A1

    公开(公告)日：2003-03-06

    申请号：US10240273

    申请日：2002-09-30

    发明人： Marc Oliver Kristen ,  Gerhard Hauck

    IPC分类号： C08F004/06 ,  B01J031/00

    CPC分类号： C08F110/02 ,  C08F10/00 ,  C08F2500/17 ,  C08F4/7042

    摘要： A catalyst system for the polymerization of olefins is prepared by initially charging one or more compounds of the formula I a or I b, 1 subsequently adding a molecularly defined activator of the formulae II a to cnull(L-H)nullnullnull(Mnull)Q1Q2Q3Q4nullnullnullnullII anull(CAr3)nullnullnull(Mnull)Q1Q2Q3Q4nullnullnullnullII bnull(Mnull)Q1Q2Q3nullnullnullII cand finally adding an alkylating agent selected from among LiR11, MgR11R12 and AlR12R13R14.

    摘要翻译： 通过最初加入一种或多种式I a或I b的化合物，随后加入式IIa至c [（LH）] + [（M'）]的分子定义的活化剂，制备用于烯烃聚合的催化剂体系。 Q1Q2Q3Q4] - IIa [（CAr3）] + [（M'）Q1Q2Q3Q4] -IIb [（M'）Q1Q2Q3] II cand最后加入选自LiR11，MgR11R12和AlR12R13R14的烷基化剂。