Invention Application
US20040176562A1 Process for preparing low-odor and storage-stable monomer-containing polyisocyanurates based on isophorone diisocyanate
审中-公开
用于制备基于异佛尔酮二异氰酸酯的低气味和储存稳定的含单体聚异氰脲酸酯的方法
- Patent Title: Process for preparing low-odor and storage-stable monomer-containing polyisocyanurates based on isophorone diisocyanate
- Patent Title (中): 用于制备基于异佛尔酮二异氰酸酯的低气味和储存稳定的含单体聚异氰脲酸酯的方法
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Application No.: US10792864Application Date: 2004-03-05
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Publication No.: US20040176562A1Publication Date: 2004-09-09
- Inventor: Stephan Kohlstruk , Manfred Kreczinski , Rainer Elm
- Applicant: DEGUSSA AG
- Applicant Address: DE Duesseldorf
- Assignee: DEGUSSA AG
- Current Assignee: DEGUSSA AG
- Current Assignee Address: DE Duesseldorf
- Priority: DE10309432.6 20030305
- Main IPC: C08G073/00
- IPC: C08G073/00

Abstract:
Process for preparing low-odor and storage-stable monomer-containing polyisocyanurates from isophorone diisocyanate, in which the partial trimerization is carried out over a period of from 2 minutes to 30 minutes in the presence of from 0.05 to 1.5% by weight, based on the weight of the diisocyanate, of a catalyst of the formula nullRnullNX3nullmnullnullmYnullwhere Ynull is a carboxylate anion having 4-8 carbon atoms, R is a null-hydroxyalkyl group having 2-6 carbon atoms and X is an alkylene group having from 2 to 3 carbon atoms and the three radicals X together with a shared nitrogen atom which may be partially null-hydroxyalkylated and the quaternary nitrogen form a tricyclic ring which may have an OH group in the null, null, or null position relative to the nitrogen and m is from 1.0 to 2.0, wherein the trimerization is carried out continuously in a tube reactor, in particular a reaction coil, in a temperature range of 20-120null C., and a pressure range from 0.5 to 5 bar and the catalyst is subsequently thermally deactivated at 100-160null C.
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