发明申请
- 专利标题: Catalyst-precursor for the production of maleic acid anhydride and method for the production thereof
- 专利标题(中): 用于生产马来酸酐的催化剂前体及其制备方法
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申请号: US10507609申请日: 2003-03-12
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公开(公告)号: US20050222435A1公开(公告)日: 2005-10-06
- 发明人: Jens Weiguny , Sebastian Storck , Mark Duda , Cornelia Dobner
- 申请人: Jens Weiguny , Sebastian Storck , Mark Duda , Cornelia Dobner
- 申请人地址: DE 67056 Ludwigshafen
- 专利权人: BASF Aktiengesellschaft
- 当前专利权人: BASF Aktiengesellschaft
- 当前专利权人地址: DE 67056 Ludwigshafen
- 优先权: DE10211449.8 20020315
- 国际申请: PCT/EP03/02509 WO 20030312
- 主分类号: C07D307/60
- IPC分类号: C07D307/60 ; B01J27/198 ; B01J35/10 ; B01J37/00 ; B01J37/04 ; B01J37/08 ; C07B61/00 ; C07C51/215 ; C07C51/25 ; C07D307/34
摘要:
A process for preparing a vanadium, phosphorus, and oxygen catalyst precursor for preparing maleic anhydride by heterogeneously catalyzed gas-phase oxidation of a hydrocarbon having at least four carbon atoms, by reacting vanadium pentoxide (I) in the presence of a primary or secondary, noncyclic or cyclic, unbranched or branched, saturated alcohol having from 3 to 6 carbon atoms (II) with a pentavalent or trivalent phosphorus compound (III) in a temperature range from 80 to 160° C. with stirring and subsequently filtering the resultant suspension, in which (a) the way in which the phosphorus compound (III) and the vanadium pentoxide (I) are combined in the presence of the alcohol (II), (b) the action of a stirring power of from 0.01 to 0.6 W/kg suspension, and/or (c) the filtration at a temperature from 65° C. to 160° C. are used to set a filtration resistance αH·η of
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