发明申请
US20050277730A1 Method for preparing functionalised polyorganosiloxane resins by redistribution in the presence of triflic acid and/or at least of one of its derivatives and non-basic inert filler 失效
通过在三氟酸和/或其至少一种衍生物和非碱性惰性填料存在下再分配制备官能化聚有机硅氧烷树脂的方法

  • 专利标题: Method for preparing functionalised polyorganosiloxane resins by redistribution in the presence of triflic acid and/or at least of one of its derivatives and non-basic inert filler
  • 专利标题(中): 通过在三氟酸和/或其至少一种衍生物和非碱性惰性填料存在下再分配制备官能化聚有机硅氧烷树脂的方法
  • 申请号: US10509060
    申请日: 2003-03-20
  • 公开(公告)号: US20050277730A1
    公开(公告)日: 2005-12-15
  • 发明人: Fernande BoissonLucile GambutGerard Mignani
  • 申请人: Fernande BoissonLucile GambutGerard Mignani
  • 优先权: FR02/03710 20020326
  • 国际申请: PCT/FR03/00888 WO 20030320
  • 主分类号: C08G77/08
  • IPC分类号: C08G77/08 C08G77/10 C08L83/00 B01J27/02
Method for preparing functionalised polyorganosiloxane resins by redistribution in the presence of triflic acid and/or at least of one of its derivatives and non-basic inert filler
摘要:
The invention provides a method for preparing functionalized polyorganosiloxane resins (POS) comprising units M: (R3SiO1/2), Q: (SiO4/2) and M′: (YaR3-aSiO1/2) and optionally D: (R2SiO2/2) and/or D′: (RYSiO2/2) and T: (RSiO3/2) and/or T′: (YSiO3/2), wherein in said units R is C1-C10 alkyl or C8-C12 aryl and Y is a functional group (such as Si—H), by redistributing POS resins, using POSf bearing functional groups M′ and/or D′ and/or in the presence of an acid catalyst such as triflic acid or one of its derivatives and a non-basic inert filler: carbon black, diatomaceous earth, zeolite or acid or neutral oxide (Al2O3, Na2O, TiO2, MgO, silica). The invention also provides said catalyst system.
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