发明申请
- 专利标题: Polymerization catalyst systems and processes therefor and therewith
- 专利标题(中): 聚合催化剂体系及其工艺及其
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申请号: US10997727申请日: 2005-03-02
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公开(公告)号: US20050288470A1公开(公告)日: 2005-12-29
- 发明人: Elizabeth Benham , Paul DesLauriers , Max McDaniel , Al Wolfe
- 申请人: Elizabeth Benham , Paul DesLauriers , Max McDaniel , Al Wolfe
- 主分类号: C08F4/12
- IPC分类号: C08F4/12 ; C08F4/22 ; C08F4/24 ; C08F4/52 ; C08F4/69 ; C08F10/00 ; C08F210/16
摘要:
A copolymer of ethylene and a higher alpha olefin, preferably 1-hexene, can be produced using an activated chromium containing catalyst system and a cocatalyst selected from the group consisting of trialkylboron, trialkylsiloxyalutninum, and a combination of trialkylboron and thalkylaluminum compounds. The polymerization process must be carefully controlled to produce a copolymer resin having an exceptionally broad molecular weight distribution, extremely high PENT ESCR values, and a natural branch profile that impacts branching preferably into the high molecular weight portion of the polymer. The resulting copolymer resin is especially useful in high stiffness pipe applications.
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