An anode for a direct liquid fuel cell in which hydrogen gas is generated as a result of a fuel oxidation or decomposition reaction. The surface of the anode which is intended to face the electrolyte chamber of the fuel cell is substantially completely covered with a polymeric material which prevents at least about 80% of the generated hydrogen gas to pass through the polymeric material into the electrolyte chamber. This Abstract is not intended to define the invention disclosed in the specification, nor intended to limit the scope of the invention in any way.