发明申请
- 专利标题: Crystalline polymers of propylene having improved processability in the molten state and process for their preparation
- 专利标题(中): 丙烯的结晶聚合物在熔融状态下具有改进的加工性能及其制备方法
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申请号: US11385711申请日: 2006-03-22
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公开(公告)号: US20060160963A1公开(公告)日: 2006-07-20
- 发明人: Giuliano Cecchin , Anteo Pelliconi , Antonio Ciarrocchi , Paolo Ferrari
- 申请人: Giuliano Cecchin , Anteo Pelliconi , Antonio Ciarrocchi , Paolo Ferrari
- 优先权: ITMI92A001337 19920529
- 主分类号: C08G85/00
- IPC分类号: C08G85/00
摘要:
Crystalline polymers and copolymers of propylene having total MIL values>2 g/10 minutes, total [η] values in tetrahydronaphthalene at 135° C.≦2.8 dl/g, Mw/Mn values>20, a fraction insoluble in xylene at 25° C.≧94, and including from 10 to 60% by weight of a fraction (A) having [η]≧2.6, are prepared by way of sequential polymerization in at least two stages, in the presence of a particular Ziegler-Natta catalysts supported on magnesium halides. These polymers have high melt strength, high mechanical properties, and are particularly adequate for the manufacture of articles by using various conversion technologies, such as for example extrusion in thin sheets to be subjected to thermoforming, as well as for injection molding, and blow molding.
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