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1.发明授权Crystalline polymers of propylene having improved processability in the molten state and process for their preparation 失效丙烯的结晶聚合物在熔融状态下具有改进的加工性能及其制备方法公开(公告)号：US07332556B2
公开(公告)日：2008-02-19
申请号：US11385711
申请日：2006-03-22
IPC分类号： C08F110/06
CPC分类号： C08F297/08 , C08F10/00 , C08F10/06 , C08F110/06 , C08F4/6465 , C08F2/001 , C08F2500/17 , C08F2500/12 , C08F2500/04 , C08F2500/11
摘要： Crystalline polymers and copolymers of propylene having total MIL values>2 g/10 minutes, total [η] values in tetrahydronaphthalene at 135° C.≦2.8 dl/g, mW/MN values>20, a fraction insoluble in xylene at 25° C.≧94, and including from 10 to 60% by weight of a fraction (A) having [η]≧2.6, are prepared by way of sequential polymerization in at least two stages, in the presence of a particular Ziegler-Natta catalysts supported on magnesium halides. These polymers have high melt strength, high mechanical properties, and are particularly adequate for the manufacture of articles by using various conversion technologies, such as for example extrusion in thin sheets to be subjected to thermoforming, as well as for injection molding, and blow molding.
摘要翻译： 总共MIL值> 2g / 10分钟的丙烯结晶聚合物和共聚物，四氢化萘在135℃时的总η= 2.8dl / g，mW / MN值> 20，在25℃下不溶于二甲苯的级分 °C = 94，并且包括10至60重量％的具有η= 2.6的级分（A），通过在至少两个阶段中的顺序聚合，在特定的齐格勒（Ziegler）的存在下制备 -Natta催化剂负载在卤化镁上。 这些聚合物具有高熔体强度，高机械性能，并且特别适用于通过使用各种转化技术制造制品，例如在薄片中挤出以进行热成型，以及用于注射成型和吹塑 。
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2.发明申请Crystalline polymers of propylene having improved processability in the molten state and process for their preparation 失效丙烯的结晶聚合物在熔融状态下具有改进的加工性能及其制备方法公开(公告)号：US20060160963A1
公开(公告)日：2006-07-20
申请号：US11385711
申请日：2006-03-22
IPC分类号： C08G85/00
CPC分类号： C08F297/08 , C08F10/00 , C08F10/06 , C08F110/06 , C08F4/6465 , C08F2/001 , C08F2500/17 , C08F2500/12 , C08F2500/04 , C08F2500/11
摘要： Crystalline polymers and copolymers of propylene having total MIL values>2 g/10 minutes, total [η] values in tetrahydronaphthalene at 135° C.≦2.8 dl/g, Mw/Mn values>20, a fraction insoluble in xylene at 25° C.≧94, and including from 10 to 60% by weight of a fraction (A) having [η]≧2.6, are prepared by way of sequential polymerization in at least two stages, in the presence of a particular Ziegler-Natta catalysts supported on magnesium halides. These polymers have high melt strength, high mechanical properties, and are particularly adequate for the manufacture of articles by using various conversion technologies, such as for example extrusion in thin sheets to be subjected to thermoforming, as well as for injection molding, and blow molding.
摘要翻译： 总共MIL值> 2g / 10分钟的丙烯的结晶聚合物和共聚物，四氢化萘在135℃下的总η= 2.8dl / g，Mw / Mn值> 20，在25℃下不溶于二甲苯的级分 °C = 94，并且包括10至60重量％的具有η= 2.6的级分（A），通过在至少两个阶段中的顺序聚合，在特定的齐格勒（Ziegler）的存在下制备 -Natta催化剂负载在卤化镁上。 这些聚合物具有高熔体强度，高机械性能，并且特别适用于通过使用各种转化技术制造制品，例如在薄片中挤出以进行热成型，以及用于注射成型和吹塑 。
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3.发明授权Crystalline polymers of propylene having improved processability in the molten state and process for their preparation 失效丙烯的结晶聚合物在熔融状态下具有改进的加工性能及其制备方法公开(公告)号：US07074871B2
公开(公告)日：2006-07-11
申请号：US10361569
申请日：2003-02-11
IPC分类号： C08F110/06
CPC分类号： C08F297/08 , C08F10/00 , C08F10/06 , C08F110/06 , C08F4/6465 , C08F2/001 , C08F2500/17 , C08F2500/12 , C08F2500/04 , C08F2500/11 , C08F2500/26
摘要： Crystalline polymers and copolymers of propylene having total MIL values>2 g/10 minutes, total [η] values in tetrahydronaphthalene at 135° C.≦2/8 dl/g, Mw/Mn values>20, a fraction insoluble in xylene at 25° C.≧94, and including from 10 to 60% by weight of a fraction (A) having [η]≧2.6, are prepared by way of sequential polymerization in at least two stages, in the presence of particular Ziegler-Natta catalysts supported on magnesium halides. These polymers have high melt strength, high mechanical properties, and are particularly adequate for the manufacture of articles by using various conversion technologies, such as for example extrusion in thin sheets to be subjected to thermoforming, as well as for injection molding, and blow molding.
摘要翻译： 总共MIL值> 2g / 10分钟的丙烯的结晶聚合物和共聚物，在四氢化萘中135℃时的总η= 2 / 8dl / g，Mw / Mn值> 20，不溶于二甲苯的级分 在25℃下，≥94，并且包括10至60重量％的具有η= 2.6的级分（A），通过在至少两个阶段中的顺序聚合制备，在特定的存在下 齐格勒 - 纳塔催化剂负载在卤化镁上。 这些聚合物具有高熔体强度，高机械性能，并且特别适用于通过使用各种转化技术制造制品，例如在薄片中挤出以进行热成型，以及用于注射成型和吹塑 。
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4.发明授权Polypropylene compositions having good transparency and improved impact resistance 失效具有良好的透明性和耐冲击性的聚丙烯组合物
公开(公告)号：US5541260A
公开(公告)日：1996-07-30
申请号：US399959
申请日：1995-03-06
CPC分类号： C08F297/08 , C08L23/10 , C08L23/0815 , C08L2308/00
摘要： Disclosed is a polymer composition containing:(A) from 70 to 98 parts by weight of a crystalline propylene homopolymer, or a crystalline random copolymer of propylene with ethylene and/or C.sub.4 -C.sub.10 .alpha.-olefins, containing from 0.5 to 10% by weight of ethylene and/or .alpha.-olefins [fraction (A)]; and(B) from 2 to 30 parts by weight of elastomeric copolymer of ethylene with one or more C.sub.4 -C.sub.10 .alpha.-olefins, containing from 60 to 85% by weight of ethylene, and partially soluble in xylene at 25.degree. C. [fraction (B)];wherein the composition has an intrinsic viscosity value in tetrahydronaphthalene at 135.degree. C. of the fraction soluble in xylene at 25.degree. C. ranging from 0.8 to 1.1 dl/g.
摘要翻译： 公开了一种聚合物组合物，其包含：（A）70至98重量份的结晶丙烯均聚物，或丙烯与乙烯和/或C 4 -C 10α-烯烃的结晶无规共聚物，其含有0.5至10重量％ 的乙烯和/或α-烯烃[级分（A）]; 和（B）2-30重量份的乙烯与一种或多种C 4 -C 10α-烯烃的弹性体共聚物，其含有60至85重量％的乙烯，并且部分可溶于25℃的二甲苯中。 （B）]; 其中所述组合物在135℃下在四氢萘中在25℃下可溶于二甲苯的级分的特性粘度值为0.8-1.1dl / g。
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5.发明授权
公开(公告)号：US5453466A
公开(公告)日：1995-09-26
申请号：US298445
申请日：1994-08-29
IPC分类号： C08F210/06 , B60R19/03 , C08F10/02 , C08F10/06 , C08F210/02 , C08K3/00 , C08L23/00 , C08L23/08 , C08L23/10 , C08L23/12 , C08L23/16 , C08L23/04
CPC分类号： C08K3/0033 , C08L23/12 , C08L2205/03 , C08L23/0815 , C08L23/16 , C08L2308/00
摘要： Disclosed are polyolefin compositionshaving high balance of stiffness and impact strength, which comprise (percentage by weight):A) 30%-60% of a propylene homopolymer or copolymer;B) 14%-30% of a fraction comprising copolymers of propylene with ethylene;C) 10%-25% of a copolymer of ethylene with a C.sub.3 -C.sub.8 .alpha.-olefin;D) 5%-45% of a mineral filler.
摘要翻译： 公开了具有高刚度和冲击强度的高平衡的聚烯烃组合物，其包含（重量百分比）：A）30％-60％的丙烯均聚物或共聚物; B）包含丙烯与乙烯的共聚物的馏分的14％-30％ C）10％-25％的乙烯与C 3 -C 8α-烯烃的共聚物; D）5％-45％矿物填料。
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6.发明授权Crystalline olefin polymers and copolymers in the form of spherical particles at high porosity 失效具有高孔隙率的球形颗粒形式的结晶烯烃聚合物和共聚物
公开(公告)号：US5231119A
公开(公告)日：1993-07-27
申请号：US718680
申请日：1991-06-21
IPC分类号： C08F4/02 , C08F2/00 , C08F4/00 , C08F4/42 , C08F8/00 , C08F10/00 , C08F10/02 , C08F12/00 , C08F110/02 , C08F210/06 , C08J3/12 , C08J3/20 , C08J3/22 , C08J9/28
CPC分类号： C08F10/00 , C08J3/12 , C08J3/226 , C08F110/02
摘要： Crystalline olefin polymers and copolymers in the form of spherical particles having porosity (expressed in percentage of voids) higher than 15%, with more than 90% of the pores having a pore diameter greater than one micron. These polymeric particulate materials find many applications, including, e.g., the preparation of masterbatches containing significant quantities of additives and/or pigments.
摘要翻译： 具有高于15％的孔隙率（以空隙百分比表示）的球形颗粒形式的结晶烯烃聚合物和共聚物，其中超过90％的孔具有大于1微米的孔径。 这些聚合物颗粒材料有许多应用，包括例如制备含有大量添加剂和/或颜料的母料。
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7.发明授权
公开(公告)号：US5296548A
公开(公告)日：1994-03-22
申请号：US763695
申请日：1991-09-23
IPC分类号： C08F210/06 , C08F2/34 , C08F210/16 , C08F297/08 , C08L23/14 , C08L23/16
CPC分类号： C08L23/14 , C08F297/08 , C08L23/142 , C08L2205/02
摘要： Discosed are compositions of crystalline propylene polymers comprising (by weight):A) 30-65% of a copolymer of propylene with a C.sub.4 -C.sub.8 .alpha.-olefin, containing from 98 to 80% propylene;B) 35-70% of a copolymer of propylene with ethylene and optionally from 2 to 10% of a C.sub.4 -C.sub.8 .alpha.-olefin, said copolymer containing 2 to 10% ethylene when the C.sub.4 -C.sub.8 .alpha.-olefin is not present, and 0.5 to 5% ethylene when the C.sub.4 -C.sub.8 .alpha.-olefin is present.
摘要翻译： 所述的结晶丙烯聚合物的组合物包含（按重量计）：A）30-65％的丙烯与含有98-80％丙烯的C 4 -C 8（α-） - 烯烃的共聚物; B）35-70％的丙烯与乙烯和任选的2至10％的C 4 -C 8（α） - 烯烃的共聚物，当C4-C8（α） - 烯烃是含有2-10％乙烯的共聚物是 不存在，当存在C4-C8（α） - 烯烃时为0.5〜5％的乙烯。
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8.发明授权Crystalline propylene polymers and copolymers in the form of spherical particles at high porosity 失效结晶丙烯聚合物和高孔隙度球形颗粒形式的共聚物
公开(公告)号：US5236962A
公开(公告)日：1993-08-17
申请号：US929470
申请日：1992-08-13
CPC分类号： C08C19/22 , C08F2/00 , C08F8/34 , Y10S526/904
摘要： Crystalline polymers and copolymers of propylene in the form of spherical particles having a porosity (expressed in percentage of voids) greater than 15%. These polymers are useful in the preparation of masterbatch containing significant quantities of additives and/or pigments.
摘要翻译： 具有孔隙率（以空隙百分比表示）的球形颗粒形式的丙烯的结晶聚合物和共聚物大于15％。 这些聚合物可用于制备含有大量添加剂和/或颜料的母料。
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