发明申请
- 专利标题: Catalytic conversion of oxygenates to olefins
- 专利标题(中): 含氧化合物催化转化成烯烃
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申请号: US11484305申请日: 2006-07-11
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公开(公告)号: US20070043250A1公开(公告)日: 2007-02-22
- 发明人: Teng Xu , Tan-Jen Chen , Neeraj Sangar , John Ou
- 申请人: Teng Xu , Tan-Jen Chen , Neeraj Sangar , John Ou
- 主分类号: C07C1/00
- IPC分类号: C07C1/00 ; B01J23/00 ; B01J29/06 ; B01J21/00
摘要:
An oxygenate conversion catalyst useful in the conversion of oxygenates such as methanol to olefinic products may be improved by the use of a catalyst combination based on a molecular sieve in combination with a co-catalyst comprising a mixed metal oxide composition which has oxidation/reduction functionality under the conditions of the conversion. This metal oxide co-catalyst component will comprise a mixed oxide of one or more, preferably at least two, transition metals, usually of Series 4, 5 or 6 of the Periodic Table, with the metals of Series 4 being preferred, as an essential component of the mixed oxide composition. The preferred transition metals are those of Groups 5, especially titanium and vanadium, Group 6, especially chromium or molybdenum, Group 7, especially manganese and Group 8, especially cobalt or nickel. Other metal oxides may also be present. The preferred molecular sieve components in these catalysts are the high silica zeolites and the SAPOs, especially the small pore SAPOs (8-membered rings), such as SAPO-34. These catalyst combinations exhibit reduced coke selectivity have the potential of achieving extended catalyst life. In addition, these catalysts have the capability of selectively converting the hydrogen produced during the conversion to liquid products, mainly water, reducing the demand on reactor volume and product handling.
公开/授权文献
- US07700816B2 Catalytic conversion of oxygenates to olefins 公开/授权日:2010-04-20
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