发明申请
US20070149730A1 Polymerization process 审中-公开
聚合过程

Polymerization process
摘要:
The invention relates to a polymerization process, the polymerization process includes contacting a cyclic bridged metallocene catalyst represented by the following formula: LA(A)LBMQn wherein A is a divalent group bound to each of LA and LB; each of LA and LB are bound to M, and each Q is bound to M; LA and LB are independently selected from the group consisting of cyclopentadienyl ligands and substituted cyclopentadienyl ligands; A is a divalent bridging group comprising a heterocyclic ring comprising from 3 to 6 carbon atoms and one silyl, thus forming a 4 to 7 member divalent ring; M is a Group 4, 5, or 6 transition metal; Q is independently a halogen, a hydride, or a hydrocarbyl radical having from 1 to 20 carbon atoms; wherein n is 1 or 2; with an activator, and optionally a support, to form an activated catalyst and, subsequently, contacting the activated catalyst with ethylene and optionally, at least one C3-C8 alpha olefin comonomer.
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