发明申请
US20080103325A1 Mixed metal oxide catalysts for the ammoxidation of propane and isobutane
审中-公开
用于丙烷和异丁烷氨氧化的混合金属氧化物催化剂
- 专利标题: Mixed metal oxide catalysts for the ammoxidation of propane and isobutane
- 专利标题(中): 用于丙烷和异丁烷氨氧化的混合金属氧化物催化剂
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申请号: US11590153申请日: 2006-10-31
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公开(公告)号: US20080103325A1公开(公告)日: 2008-05-01
- 发明人: Claus Lugmair , Benjamin Mork , Jessica Zysk Fryer , Anthony F. Volpe , Joseph Peter Bartek , Hailian Li , Alakananda Bhattacharyya , James F. Brazdil , Bruce I. Rosen , Eric Moore
- 申请人: Claus Lugmair , Benjamin Mork , Jessica Zysk Fryer , Anthony F. Volpe , Joseph Peter Bartek , Hailian Li , Alakananda Bhattacharyya , James F. Brazdil , Bruce I. Rosen , Eric Moore
- 主分类号: C07C253/26
- IPC分类号: C07C253/26
摘要:
A catalyst composition comprising molybdenum, vanadium, antimony niobium, at least one element select from the group consisting of titanium, tin, germanium, zirconium, and hafnium, and at least one lanthanide selected from the group consisting of lanthanum, praseodymium, neodymium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium and lutetium; with the proviso that catalyst contains germanium (in the absence of at last one of titanium, tin, zirconium, hafnium) only in combination with neodymium and/or praseodymium and no other lanthanides. Such catalyst compositions are effective for the gas-phase conversion of propane to acrylonitrile and isobutane to methacrylonitrile (via ammoxidation).