公开(公告)号：US20060120923A1

公开(公告)日：2006-06-08

申请号：US11252530

申请日：2005-10-17

申请人： Timothy Swager ,  Jye-Shane Yang ,  Vance Williams ,  Yi-Jun Miao ,  Claus Lugmair ,  Igor Levitsky ,  Jinsang Kim ,  Robert Deans

发明人： Timothy Swager ,  Jye-Shane Yang ,  Vance Williams ,  Yi-Jun Miao ,  Claus Lugmair ,  Igor Levitsky ,  Jinsang Kim ,  Robert Deans

IPC分类号： G01N21/00

CPC分类号： C08L101/12 ,  B82Y10/00 ,  C08F257/02 ,  C08G61/00 ,  C08G61/10 ,  C08L65/00 ,  C09K9/02 ,  C09K11/06 ,  G01N21/6428 ,  G01N21/643 ,  G01N21/7703 ,  G01N2021/7786 ,  H01L51/0035 ,  H01L51/0043 ,  H01L51/0044 ,  H01L51/0052 ,  H01L51/0077 ,  H01L51/0545 ,  H01L51/0595 ,  H01L51/428 ,  H01L51/5012 ,  Y02E10/549 ,  C08F232/00

摘要： The present invention relates to a class of luminescent and conductive polymer compositions having chromophores, and particularly solid films of these compositions exhibiting increased luminescent lifetimes, quantum yields and amplified emissions. These desirable properties can be provided through polymers having rigid groups designed to prevent polymer reorganization, aggregation or π-stacking upon solidification. These polymers can also display an unusually high stability with respect to solvent and heat exposures. The invention also relates to a sensor and a method for sensing an analyte through the luminescent and conductive properties of these polymers. Analytes can be sensed by activation of a chromophore at a polymer surface. Analytes include aromatics, phosphate ester groups and in particular explosives and chemical warfare agents in a gaseous state. The present invention also relates to devices and methods for amplifying emissions by incorporating a polymer having an energy migration pathway and/or providing the polymer as a block co-polymer or as a multi-layer.

公开(公告)号：US20070007372A1

公开(公告)日：2007-01-11

申请号：US11519358

申请日：2006-09-11

申请人： Claus Lugmair ,  Alfred Hagemeyer ,  Lynn Van Erden ,  Anthony Volpe ,  David Lowe ,  Yumin Liu

发明人： Claus Lugmair ,  Alfred Hagemeyer ,  Lynn Van Erden ,  Anthony Volpe ,  David Lowe ,  Yumin Liu

IPC分类号： B02C1/00

CPC分类号： B07B1/00 ,  B01J19/0046 ,  B01J35/10 ,  B01J37/0036 ,  B01J37/009 ,  B01J2219/00313 ,  B01J2219/00319 ,  B01J2219/00351 ,  B01J2219/00481 ,  B01J2219/00484 ,  B01J2219/00495 ,  B01J2219/00585 ,  B01J2219/007 ,  B01J2219/00704 ,  B01J2219/00745 ,  B01J2219/00747 ,  B01J2219/00756 ,  B01L3/5025 ,  B22F2998/00 ,  C40B30/08 ,  C40B40/18 ,  G01N31/10 ,  B22F9/04

摘要： Methods and apparatus for combinatorial (i.e., high-throughput) materials research, such as catalysis research, that involves parallel apparatus for simultaneously effecting mechanical treatments such as grinding, mixing, pressing, crushing, sieving, and/or fractionating of such materials are disclosed. The methods and apparatus are useful for mechanically treating catalysis materials and other solid materials, including without limitation, electronic materials such as phosphors, colorants such as pigments, and pharmaceuticals such as crystalline drugs or drug candidates. The simultaneous protocols and parallel apparatus offer substantial improvements in overall throughput for preparing arrays of materials, such as catalysis materials.

摘要翻译： 公开了用于组合（即，高通量）材料研究的方法和装置，例如催化研究，涉及用于同时进行诸如研磨，混合，压制，粉碎，筛分和/或分级的机械处理的并行装置。 。 所述方法和装置可用于机械处理催化材料和其它固体材料，包括但不限于电子材料如磷光体，着色剂如颜料，以及药物如结晶药物或药物候选物。 同时协议和并行设备在制备材料阵列（例如催化材料）方面提供总体通量的显着改进。

公开(公告)号：US20060120917A1

公开(公告)日：2006-06-08

申请号：US11252419

申请日：2005-10-17

申请人： Timothy Swager ,  Jye-Shane Yang ,  Vance Williams ,  Yi-Jun Miao ,  Claus Lugmair ,  Igor Levitsky ,  Jinsang Kim ,  Robert Deans

发明人： Timothy Swager ,  Jye-Shane Yang ,  Vance Williams ,  Yi-Jun Miao ,  Claus Lugmair ,  Igor Levitsky ,  Jinsang Kim ,  Robert Deans

IPC分类号： G01N21/00

CPC分类号： C08L101/12 ,  B82Y10/00 ,  C08F257/02 ,  C08G61/00 ,  C08G61/10 ,  C08L65/00 ,  C09K9/02 ,  C09K11/06 ,  G01N21/6428 ,  G01N21/643 ,  G01N21/7703 ,  G01N2021/7786 ,  H01L51/0035 ,  H01L51/0043 ,  H01L51/0044 ,  H01L51/0052 ,  H01L51/0077 ,  H01L51/0545 ,  H01L51/0595 ,  H01L51/428 ,  H01L51/5012 ,  Y02E10/549 ,  C08F232/00

摘要： The present invention relates to a class of luminescent and conductive polymer compositions having chromophores, and particularly solid films of these compositions exhibiting increased luminescent lifetimes, quantum yields and amplified emissions. These desirable properties can be provided through polymers having rigid groups designed to prevent polymer reorganization, aggregation or π-stacking upon solidification. These polymers can also display an unusually high stability with respect to solvent and heat exposures. The invention also relates to a sensor and a method for sensing an analyte through the luminescent and conductive properties of these polymers. Analytes can be sensed by activation of a chromophore at a polymer surface. Analytes include aromatics, phosphate ester groups and in particular explosives and chemical warfare agents in a gaseous state. The present invention also relates to devices and methods for amplifying emissions by incorporating a polymer having an energy migration pathway and/or providing the polymer as a block co-polymer or as a multi-layer.

公开(公告)号：US20050054869A1

公开(公告)日：2005-03-10

申请号：US10860369

申请日：2004-06-03

申请人： Claus Lugmair ,  Jessica Zysk ,  Robert Grasselli

发明人： Claus Lugmair ,  Jessica Zysk ,  Robert Grasselli

IPC分类号： B01J23/00 ,  B01J23/14 ,  B01J23/18 ,  B01J23/20 ,  B01J23/28 ,  B01J37/10 ,  C07C51/215 ,  C07C253/24 ,  C07C255/08 ,  C07C253/26 ,  C07C51/16

CPC分类号： C07C51/215 ,  B01J23/002 ,  B01J23/14 ,  B01J23/18 ,  B01J23/20 ,  B01J23/28 ,  B01J37/10 ,  B01J2523/00 ,  C07C253/24 ,  Y02P20/52 ,  C07C57/04 ,  C07C255/08 ,  B01J2523/42 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/64 ,  B01J2523/68 ,  B01J2523/53

摘要： Compositions of matter and catalyst compositions effective for gas-phase conversion of propane to acrylic acid (via oxidation) or to acrylonitrile (via ammoxidation) and isobutane to methacrylic acid (via oxidation) and isobutane to methacrylonitrile (via ammoxidation) are disclosed. Preferred catalyst compositions comprise molybdenum, vanadium, niobium, antimony and germanium and molybdenum, vanadium, tantalum, antimony, and germanium. Methods of preparing such compositions and related compositions, including hydrothermal synthesis methods are also disclosed. The preferred catalysts convert propane to acrylic acid and/or to acrylonitrile and isobutane to methacrylic acid/methacrylonitrile with a yield of at least about 50%.

摘要翻译： 公开了将丙烷气相转化为丙烯酸（通过氧化）或丙烯腈（通过氨氧化）和异丁烷至甲基丙烯酸（经由氧化）和异丁烷至甲基丙烯腈（通过氨氧化））的物质和催化剂组合物的组合物。 优选的催化剂组合物包括钼，钒，铌，锑和锗以及钼，钒，钽，锑和锗。 还公开了制备这种组合物和相关组合物的方法，包括水热合成方法。 优选的催化剂将丙烷转化为丙烯酸和/或将丙烯腈和异丁烷转化成甲基丙烯酸/甲基丙烯腈，产率至少为约50％。

公开(公告)号：US20070289903A1

公开(公告)日：2007-12-20

申请号：US11845937

申请日：2007-08-28

申请人： Claus Lugmair ,  Alfred Hagemeyer ,  Lynn Erden ,  Anthony Volpe ,  David Lowe ,  Yumin Liu

发明人： Claus Lugmair ,  Alfred Hagemeyer ,  Lynn Erden ,  Anthony Volpe ,  David Lowe ,  Yumin Liu

IPC分类号： B07B1/00

CPC分类号： B07B1/00 ,  B01J19/0046 ,  B01J35/10 ,  B01J37/0036 ,  B01J37/009 ,  B01J2219/00313 ,  B01J2219/00319 ,  B01J2219/00351 ,  B01J2219/00481 ,  B01J2219/00484 ,  B01J2219/00495 ,  B01J2219/00585 ,  B01J2219/007 ,  B01J2219/00704 ,  B01J2219/00745 ,  B01J2219/00747 ,  B01J2219/00756 ,  B01L3/5025 ,  B22F2998/00 ,  C40B30/08 ,  C40B40/18 ,  G01N31/10 ,  B22F9/04

摘要： Methods and apparatus for combinatorial (i.e., high-throughput) materials research, such as catalysis research, that involves parallel apparatus for simultaneously effecting mechanical treatments such as grinding, mixing, pressing, crushing, sieving, and/or fractionating of such materials are disclosed. The methods and apparatus are useful for mechanically treating catalysis materials and other solid materials, including without limitation, electronic materials such as phosphors, colorants such as pigments, and pharmaceuticals such as crystalline drugs or drug candidates. The simultaneous protocols and parallel apparatus offer substantial improvements in overall throughput for preparing arrays of materials, such as catalysis materials.

摘要翻译： 公开了用于组合（即，高通量）材料研究的方法和装置，例如催化研究，涉及用于同时进行诸如研磨，混合，压制，粉碎，筛分和/或分级的机械处理的并行装置。 。 所述方法和装置可用于机械处理催化材料和其它固体材料，包括但不限于电子材料如磷光体，着色剂如颜料，以及药物如结晶药物或候选药物。 同时协议和并行设备在制备材料阵列（例如催化材料）方面提供总体通量的显着改进。

公开(公告)号：US06971593B2

公开(公告)日：2005-12-06

申请号：US10641906

申请日：2003-08-15

申请人： Claus Lugmair ,  Alfred Hagemeyer ,  Lynn Van Erden ,  Anthony F. Volpe, Jr. ,  David M. Lowe ,  Yumin Liu

发明人： Claus Lugmair ,  Alfred Hagemeyer ,  Lynn Van Erden ,  Anthony F. Volpe, Jr. ,  David M. Lowe ,  Yumin Liu

IPC分类号： B01J19/00 ,  B01J37/00 ,  C40B30/08 ,  C40B40/18 ,  G01N31/10 ,  B02C19/12

CPC分类号： B07B1/00 ,  B01J19/0046 ,  B01J35/10 ,  B01J37/0036 ,  B01J37/009 ,  B01J2219/00313 ,  B01J2219/00319 ,  B01J2219/00351 ,  B01J2219/00481 ,  B01J2219/00484 ,  B01J2219/00495 ,  B01J2219/00585 ,  B01J2219/007 ,  B01J2219/00704 ,  B01J2219/00745 ,  B01J2219/00747 ,  B01J2219/00756 ,  B01L3/5025 ,  B22F2998/00 ,  C40B30/08 ,  C40B40/18 ,  G01N31/10 ,  B22F9/04

摘要： Methods and apparatus for combinatorial (i.e., high-throughput) materials research, such as catalysis research, that involves parallel apparatus for simultaneously effecting mechanical treatments such as grinding, mixing, pressing, crushing, sieving, and/or fractionating of such materials are disclosed. The methods and apparatus are useful for mechanically treating catalysis materials and other solid materials, including without limitation, electronic materials such as phosphors, colorants such as pigments, and pharmaceuticals such as crystalline drugs or drug candidates. The simultaneous protocols and parallel apparatus offer substantial improvements in overall throughput for preparing arrays of materials, such as catalysis materials.

摘要翻译： 公开了用于组合（即，高通量）材料研究的方法和装置，例如催化研究，涉及用于同时进行诸如研磨，混合，压制，粉碎，筛分和/或分级的机械处理的并行装置。 。 所述方法和装置可用于机械处理催化材料和其它固体材料，包括但不限于电子材料如磷光体，着色剂如颜料，以及药物如结晶药物或药物候选物。 同时协议和并行设备在制备材料阵列（例如催化材料）方面提供总体通量的显着改进。

公开(公告)号：US20130102819A1

公开(公告)日：2013-04-25

申请号：US13276403

申请日：2011-10-19

申请人： Normen Szesni ,  Alfred Hagemeyer ,  Frank Grossmann ,  Richard Fischer ,  Michael Urbancic ,  Claus Lugmair ,  Mingyong Sun ,  Hongyi C. Hou ,  David Michael Lowe

发明人： Normen Szesni ,  Alfred Hagemeyer ,  Frank Grossmann ,  Richard Fischer ,  Michael Urbancic ,  Claus Lugmair ,  Mingyong Sun ,  Hongyi C. Hou ,  David Michael Lowe

IPC分类号： C07C5/09 ,  B01J23/50 ,  B01J23/52 ,  B01J31/02 ,  B01J23/62 ,  B01J23/89 ,  B01J23/644 ,  B01J23/58 ,  B01J23/44 ,  B01J23/60

CPC分类号： B01J23/44 ,  B01J21/04 ,  B01J23/50 ,  B01J23/52 ,  B01J23/58 ,  B01J23/60 ,  B01J23/62 ,  B01J23/626 ,  B01J23/628 ,  B01J23/6447 ,  B01J23/8926 ,  B01J31/0277 ,  B01J31/0279 ,  B01J31/0284 ,  B01J35/008 ,  B01J35/1009 ,  B01J35/1038 ,  B01J37/0201 ,  B01J37/024 ,  B01J37/16 ,  B01J2231/645 ,  B01J2531/824 ,  C07C7/167 ,  C10G45/40 ,  C10G2400/20 ,  Y02P20/52 ,  C07C11/04 ,  C07C11/06

摘要： This invention relates to heterogeneous catalysts useful for selective hydrogenation of unsaturated hydrocarbons, comprising palladium and optionally a promoter, supported on a substrate, having an uncoated BET surface area of ≦9 m2/g, the surface being coated with an ionic liquid. Also described are methods of making the catalysts and methods of selective hydrogenation of acetylene and/or dienes in front-end mixed olefin feed streams.

摘要翻译： 本发明涉及可用于不饱和烃的选择性氢化的非均相催化剂，其包含负载在基材上的钯和任选的助催化剂，其具有未涂覆的BET表面积为9m 2 / g，该表面用离子液体涂覆。 还描述了制备催化剂的方法和在前端混合烯烃进料流中乙炔和/或二烯烃的选择性氢化的方法。

公开(公告)号：US20090005586A1

公开(公告)日：2009-01-01

申请号：US11771278

申请日：2007-06-29

申请人： James F. Brazdil, JR. ,  Bruce I. Rosen ,  Eric Moore ,  Joseph P. Bartek ,  Claus Lugmair ,  Benjamin Mork

发明人： James F. Brazdil, JR. ,  Bruce I. Rosen ,  Eric Moore ,  Joseph P. Bartek ,  Claus Lugmair ,  Benjamin Mork

IPC分类号： C07C253/24 ,  B01J21/08 ,  B01J23/10 ,  B01J27/057

CPC分类号： C07C253/24 ,  B01J23/002 ,  B01J23/30 ,  B01J37/10 ,  B01J2523/00 ,  Y02P20/52 ,  C07C255/08 ,  B01J2523/3725 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/69

摘要： A catalyst composition comprising molybdenum, vanadium, and antimony, and at least one other element selected from the group consisting of praseodymium, neodymium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium. Such catalyst compositions are effective for the gas-phase conversion of propane to acrylonitrile and isobutane to methacrylonitrile (via ammoxidation).

摘要翻译： 包含钼，钒和锑的催化剂组合物以及选自镨，钕，钐，铕，钆，铽，镝，钬，铒，ium，镱和镥中的至少一种其它元素。 这种催化剂组合物可有效地将丙烷气相转化为丙烯腈和异丁烷至甲基丙烯腈（通过氨氧化）。

公开(公告)号：US20080103326A1

公开(公告)日：2008-05-01

申请号：US11590154

申请日：2006-10-31

申请人： Bruce Irwin Rosen ,  Eric Moore ,  James F. Brazdil ,  Claus Lugmair ,  Bren Ehnebuske

发明人： Bruce Irwin Rosen ,  Eric Moore ,  James F. Brazdil ,  Claus Lugmair ,  Bren Ehnebuske

IPC分类号： C07C253/26 ,  B01J23/10

CPC分类号： C07C253/24 ,  B01J23/002 ,  B01J23/28 ,  B01J37/10 ,  B01J2523/00 ,  Y02P20/52 ,  C07C255/08 ,  B01J2523/37 ,  B01J2523/47 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/68 ,  B01J2523/11

摘要： A catalyst composition comprising molybdenum, vanadium, antimony, niobium, lithium, at least one element select from the group consisting of titanium, tin, germanium, zirconium, hafnium and at least one lanthanide selected from the group consisting of lanthanum, cerium, praseodymium, neodymium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium. Such catalyst compositions are effective for the gas-phase conversion of propane to acrylonitrile and isobutane to methacrylonitrile (via ammoxidation).

摘要翻译： 一种催化剂组合物，其包含钼，钒，锑，铌，锂，选自钛，锡，锗，锆，铪和至少一种选自镧，铈，镨， 钕，钐，铕，钆，铽，镝，钬，铒，ium，镱和镥。 这种催化剂组合物可有效地将丙烷气相转化为丙烯腈和异丁烷至甲基丙烯腈（通过氨氧化）。

公开(公告)号：US20080103325A1

公开(公告)日：2008-05-01

申请号：US11590153

申请日：2006-10-31

申请人： Claus Lugmair ,  Benjamin Mork ,  Jessica Zysk Fryer ,  Anthony F. Volpe ,  Joseph Peter Bartek ,  Hailian Li ,  Alakananda Bhattacharyya ,  James F. Brazdil ,  Bruce I. Rosen ,  Eric Moore

发明人： Claus Lugmair ,  Benjamin Mork ,  Jessica Zysk Fryer ,  Anthony F. Volpe ,  Joseph Peter Bartek ,  Hailian Li ,  Alakananda Bhattacharyya ,  James F. Brazdil ,  Bruce I. Rosen ,  Eric Moore

IPC分类号： C07C253/26

CPC分类号： C07C253/24 ,  B01J2523/00 ,  C07C255/08 ,  B01J2523/3756 ,  B01J2523/47 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/68 ,  B01J2523/3725 ,  B01J2523/3737 ,  B01J2523/3706 ,  B01J2523/3718 ,  B01J2523/3743 ,  B01J2523/375 ,  B01J2523/3762 ,  B01J2523/3768 ,  B01J2523/3775 ,  B01J2523/3781 ,  B01J2523/3787 ,  B01J2523/3793 ,  B01J2523/3712 ,  B01J2523/11

摘要： A catalyst composition comprising molybdenum, vanadium, antimony niobium, at least one element select from the group consisting of titanium, tin, germanium, zirconium, and hafnium, and at least one lanthanide selected from the group consisting of lanthanum, praseodymium, neodymium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium and lutetium; with the proviso that catalyst contains germanium (in the absence of at last one of titanium, tin, zirconium, hafnium) only in combination with neodymium and/or praseodymium and no other lanthanides. Such catalyst compositions are effective for the gas-phase conversion of propane to acrylonitrile and isobutane to methacrylonitrile (via ammoxidation).

摘要翻译： 一种催化剂组合物，其包含钼，钒，锑铌，至少一种选自钛，锡，锗，锆和铪的元素，以及至少一种选自镧，镨，钕，钐的镧系元素 铕，钆，铽，镝，钬，铒，ium，镱和镥; 条件是催化剂仅与钕和/或镨组合而不与其他镧系元素结合使用锗（不存在钛，锡，锆，铪中的最后一种）。 这种催化剂组合物可有效地将丙烷气相转化为丙烯腈和异丁烷至甲基丙烯腈（通过氨氧化）。