Invention Application
US20080108779A1 Process for producing polyester with metal phosphonic acid complex catalysts
审中-公开
用金属膦酸配合物催化剂生产聚酯的方法
- Patent Title: Process for producing polyester with metal phosphonic acid complex catalysts
- Patent Title (中): 用金属膦酸配合物催化剂生产聚酯的方法
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Application No.: US11901478Application Date: 2007-09-17
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Publication No.: US20080108779A1Publication Date: 2008-05-08
- Inventor: Stephen Andrews , Jianzhao Wang , Thomas Thompson , Paragkumar Thanki , Deepak Rane , Suhas Sahasrabudhe , Preetam Ghogale , Paul Odorisio , Si Wu
- Applicant: Stephen Andrews , Jianzhao Wang , Thomas Thompson , Paragkumar Thanki , Deepak Rane , Suhas Sahasrabudhe , Preetam Ghogale , Paul Odorisio , Si Wu
- Main IPC: C08G63/02
- IPC: C08G63/02

Abstract:
Disclosed is a method for the preparation of a polyester, which method comprises in a first step, reacting a dicarboxylic acid or a C1-C4 dicarboxylic diester with a diol at a suitable temperature and pressure to effect esterification or transesterification to prepare a precondensate and in a second step, reacting the precondensate to effect polycondensation at a suitable temperature and pressure to prepare a high molecular weight polyester, where a metal phosphonic acid complex compound of the formula is employed in the first step, in the second step or in both the first and second steps as a reaction catalyst; and wherein n is 0, 1, 2, 3, 4, 5 or 6; p is an integer from 1 to 30; M is a metal selected from the group consisting of Li, Na, K, Cs, Be, Ca, Mg, Sr, Ba, Al, Sb, Cd, Mn, Fe, Co, Ni, Cu and Zn; v is the valency of the metal M and is 1, 2 or 3; q is an integer from 1 to 20 where q=2p/v; and R1 is hydrogen, straight or branched chain alkyl of 1 to 36 carbon atoms, straight or branched chain alkenyl of 1 to 36 carbon atoms, cycloalkyl of 5 to 8 carbon atoms or aryl of 6 to 10 carbon atoms; or is said alkyl, alkenyl, cycloalkyl or aryl substituted by one to four hydroxyl, halogen, straight or branched chain alkoxy of 1 to 8 carbon atoms, straight or branched chain alkyl of 1 to 8 carbon atoms or amino groups. The metal complex catalyst compound is in particular
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