发明申请
- 专利标题: Catalyst for oxidation of saturated and unsaturated aldehydes to unsaturated carboxylic acid, method of making and method of using thereof
- 专利标题(中): 用于将饱和和不饱和醛氧化成不饱和羧酸的催化剂,其制备方法及其使用方法
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申请号: US11702395申请日: 2007-02-05
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公开(公告)号: US20080188681A1公开(公告)日: 2008-08-07
- 发明人: Wugeng Liang , Paul E. Ellis , Joseph R. Linzer
- 申请人: Wugeng Liang , Paul E. Ellis , Joseph R. Linzer
- 专利权人: Saudi Basic Industries Corporation
- 当前专利权人: Saudi Basic Industries Corporation
- 主分类号: C07C51/235
- IPC分类号: C07C51/235 ; B01J27/199 ; C01B25/37
摘要:
The invention is a supported or bound heteropoly acid catalyst composition, a method of making the catalyst composition and a process for the oxidation of saturated and/or unsaturated aldehydes to unsaturated carboxylic acids using the catalyst composition. The catalyst composition has a heteropoly acid component containing molybdenum, vanadium, phosphorus and cesium and support/binder having a surface area of about 0.1 m2/g to about 1.0 m2/g.The catalyst is made by dissolving compounds of the components of each of the heteropoly acid compounds in a solution, precipitating the heteropoly acid compounds, contacting the heteropoly acid compounds to form a catalyst precursor and calcining the catalyst precursor to form a heteropoly acid compound catalyst.Unsaturated aldehydes, such as methacrolein, may be oxidized in the presence of the heteropoly acid compound catalyst to produce an unsaturated carboxylic acid, such as methacrylic acid.
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