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64 条记录 (耗时 0.023 秒)

    Catalyst for oxidation of saturated and unsaturated aldehydes to unsaturated carboxylic acid, method of making and method of using thereof
    1.
    发明授权
    Catalyst for oxidation of saturated and unsaturated aldehydes to unsaturated carboxylic acid, method of making and method of using thereof 有权
    用于将饱和和不饱和醛氧化成不饱和羧酸的催化剂，其制备方法及其使用方法

    公开(公告)号：US08178718B2

    公开(公告)日：2012-05-15

    申请号：US11702395

    申请日：2007-02-05

    申请人： Wugeng Liang ,  Paul E. Ellis ,  Joseph R. Linzer

    发明人： Wugeng Liang ,  Paul E. Ellis ,  Joseph R. Linzer

    IPC分类号： C07C51/235 ,  B01J23/887

    CPC分类号： B01J27/199 ,  B01J23/002 ,  B01J35/023 ,  B01J35/1009 ,  B01J35/1038 ,  B01J37/0036 ,  B01J37/03 ,  B01J37/04 ,  B01J2523/00 ,  C07C51/252 ,  C07C57/04 ,  B01J2523/15 ,  B01J2523/17 ,  B01J2523/305 ,  B01J2523/51 ,  B01J2523/53 ,  B01J2523/54 ,  B01J2523/55 ,  B01J2523/68

    摘要： The invention is a supported or bound heteropoly acid catalyst composition, a method of making the catalyst composition and a process for the oxidation of saturated and/or unsaturated aldehydes to unsaturated carboxylic acids using the catalyst composition. The catalyst composition has a heteropoly acid component containing molybdenum, vanadium, phosphorus and cesium and support/binder having a surface area of about 0.1 m2/g to about 1.0 m2/g. The catalyst is made by dissolving compounds of the components of each of the heteropoly acid compounds in a solution, precipitating the heteropoly acid compounds, contacting the heteropoly acid compounds to form a catalyst precursor and calcining the catalyst precursor to form a heteropoly acid compound catalyst. Unsaturated aldehydes, such as methacrolein, may be oxidized in the presence of the heteropoly acid compound catalyst to produce an unsaturated carboxylic acid, such as methacrylic acid.

    摘要翻译： 本发明是负载或结合的杂多酸催化剂组合物，制备催化剂组合物的方法和使用催化剂组合物将饱和和/或不饱和醛氧化成不饱和羧酸的方法。 催化剂组合物具有包含钼，钒，磷和铯的杂多酸组分和表面积为约0.1m 2 / g至约1.0m 2 / g的载体/粘合剂。 将各种杂多酸化合物的组分的化合物溶解在溶液中，沉淀杂多酸化合物，使杂多酸化合物接触形成催化剂前体并煅烧催化剂前体以形成杂多酸化合物催化剂来制备催化剂。 不饱和醛如甲基丙烯醛可在杂多酸化合物催化剂存在下被氧化，生成不饱和羧酸，如甲基丙烯酸。

    Aromatization of alkanes using a germanium-zeolite catalyst
    2.
    发明授权
    Aromatization of alkanes using a germanium-zeolite catalyst 有权
    使用锗 - 沸石催化剂的烷烃芳构化

    公开(公告)号：US07902413B2

    公开(公告)日：2011-03-08

    申请号：US11786590

    申请日：2007-04-12

    申请人： Scott A. Stevenson ,  Dustin B. Farmer ,  Scott F. Mitchell ,  Gopalakrishnan G. Juttu ,  Alla K. Khanmamedova ,  Paul E. Ellis

    发明人： Scott A. Stevenson ,  Dustin B. Farmer ,  Scott F. Mitchell ,  Gopalakrishnan G. Juttu ,  Alla K. Khanmamedova ,  Paul E. Ellis

    IPC分类号： C07C2/76

    CPC分类号： C07C5/415 ,  B01J23/42 ,  B01J29/04 ,  B01J29/047 ,  B01J2229/18 ,  B01J2229/186 ,  C07C5/417 ,  C07C2529/44 ,  C10G45/68 ,  C10G45/70 ,  Y02P20/52 ,  C07C15/06

    摘要： This invention relates to a process for the aromatization of C6 to C12 alkanes, such as hexane, heptane and octane, to aromatics, such as benzene, ethyl benzene, toluene and xylenes, with a germanium-containing zeolite catalyst. The catalyst is a non-acidic aluminum-silicon-germanium zeolite on which a noble metal, such as platinum, has been deposited. The zeolite structure may be of MFI, BEA, MOR, LTL or MTT. The zeolite is made non-acidic by being base-exchanged with an alkali metal or alkaline earth metal, such as cesium, potassium, sodium, rubidium, barium, calcium, magnesium and mixtures thereof, to reduce acidity. The catalyst is sulfur tolerant and may be pretreated with a sulfur compound, i.e., sulfided. The hydrocarbon feed may contain sulfur up to 1000 ppm. The present invention could be applicable to a feedstream which is predominantly paraffinic and/or low in naphthenes. Lowering the hydrogen to hydrocarbon ratio increases conversion and aromatics selectivity.

    摘要翻译： 本发明涉及一种使用含锗沸石催化剂将C6至C12烷烃如己烷，庚烷和辛烷芳构化成芳族化合物如苯，乙苯，甲苯和二甲苯的方法。 催化剂是沉积贵金属如铂的非酸性铝硅锗沸石。 沸石结构可以是MFI，BEA，MOR，LTL或MTT。 沸石通过与碱金属或碱土金属如铯，钾，钠，铷，钡，钙，镁及其混合物进行碱交换而制成非酸性，以降低酸度。 催化剂是耐硫的，并且可以用硫化合物预处理，即硫化。 烃进料可含有高达1000ppm的硫。 本发明可以应用于主要是石蜡和/或低环烷烃的进料流。 降低氢气与烃的比例会提高转化率和芳烃选择性。

    Preparation of porphyrins and their metal complexes
    5.
    发明授权
    Preparation of porphyrins and their metal complexes 失效
    卟啉及其金属络合物的制备

    公开(公告)号：US5659029A

    公开(公告)日：1997-08-19

    申请号：US575783

    申请日：1995-12-22

    申请人： Paul E. Ellis, Jr. ,  Wayne A. Langdale

    发明人： Paul E. Ellis, Jr. ,  Wayne A. Langdale

    IPC分类号： C07D487/22 ,  C09B47/00

    CPC分类号： C07D487/22

    摘要： A hydroxyl-containing pyrrolic compound having a hydroxyl group or a hydroxyl-containing group in the 2-position, optionally substituted in the beta positions, is condensed in an acidified two immiscible phase solvent system to produce excellent yields of the corresponding porphyrin or metal porphyrin.

    摘要翻译： 在2-位具有羟基或含羟基的羟基的吡咯化合物任选在β位置被取代，在酸化的两个不混溶相溶剂体系中缩合，以产生相应的卟啉或金属卟啉的极好产率 。

    Reactions catalyzed by haloporphyrins
    7.
    发明授权
    Reactions catalyzed by haloporphyrins 失效
    由卟啉催化的反应

    公开(公告)号：US5489716A

    公开(公告)日：1996-02-06

    申请号：US303105

    申请日：1994-09-07

    申请人： Paul E. Ellis, Jr. ,  James E. Lyons

    发明人： Paul E. Ellis, Jr. ,  James E. Lyons

    IPC分类号： B01J31/22 ,  B01J27/24 ,  B01J31/18 ,  C07B61/00 ,  C07C27/00 ,  C07C27/12 ,  C07C29/132 ,  C07C29/50 ,  C07C31/12 ,  C07C45/33 ,  C07C45/34 ,  C07C45/35 ,  C07C45/36 ,  C07C45/53 ,  C07C51/215 ,  C07C51/235 ,  C07C51/245 ,  C07C51/25 ,  C07C51/265 ,  C07C409/16 ,  C07D487/22 ,  C07F15/02

    CPC分类号： C07D487/22 ,  B01J27/24 ,  B01J31/1815 ,  C07C29/132 ,  C07C29/50 ,  C07C45/33 ,  C07C45/34 ,  C07C45/35 ,  C07C45/36 ,  C07C45/53 ,  C07C51/215 ,  C07C51/235 ,  C07C51/245 ,  C07C51/25 ,  C07C51/252 ,  C07C51/265 ,  C07F15/025 ,  B01J2231/482 ,  B01J2531/025 ,  B01J2531/842

    摘要： The invention provides novel methods for the oxidation of hydrocarbons with oxygen-containing gas to form hydroxy-group containing compounds and for the decomposition of hydroperoxides to form hydroxygroup containing compounds. The catalysts used in the methods of the invention comprise transition metal complexes of a porphyrin ring having 1 to 12 halogen substituents on the porphyrin ring, at least one of said halogens being in a meso position and/or the catalyst containing no aryl group in a meso position. The catalyst compositions are prepared by halogenating a transition metal complex of a porphyrin. In one embodiment, a complex of a porphyrin with a metal whose porphyrin complexes are not active for oxidation of alkanes is halogenated, thereby to obtain a haloporphyrin complex of that metal, the metal is removed from the haloporphyrin complex to obtain the free base form of the haloporphyrin, and a metal such as iron whose porphyrin complexes are active for oxidation of alkanes and for the decomposition of alkyl hydroperoxides is complexed with the free base to obtain an active catalyst for oxidation of alkanes and decomposition of alkyl hydroperoxides.

    摘要翻译： 本发明提供了用含氧气体氧化烃类以形成含羟基化合物和氢过氧化物分解形成含羟基化合物的新方法。 用于本发明方法的催化剂包括在卟啉环上具有1至12个卤素取代基的卟啉环的过渡金属络合物，所述卤素中的至少一个位于中间位置和/或不含芳​​基的催化剂 中观位置。 通过卤化卟啉的过渡金属络合物制备催化剂组合物。 在一个实施方案中，卟啉与卟啉络合物对于烷烃氧化不起作用的金属的络合物被卤化，从而获得该金属的卤卟啉络合物，从卤卟啉络合物中除去金属，得到游离碱形式 卤卟啉和卟啉配合物对烷烃氧化和烷基氢过氧化物的分解具有活性的金属如铁，与游离碱络合，得到烷烃氧化和烷基氢过氧化物分解的活性催化剂。