发明申请
- 专利标题: Supported metallocene catalysts
- 专利标题(中): 负载金属茂催化剂
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申请号: US11804483申请日: 2007-05-18
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公开(公告)号: US20080287619A1公开(公告)日: 2008-11-20
- 发明人: William Gauthier , David Rauscher , Jun Tian , Nathan Williams
- 申请人: William Gauthier , David Rauscher , Jun Tian , Nathan Williams
- 主分类号: B01J31/14
- IPC分类号: B01J31/14 ; C08F4/46
摘要:
Method employing a supported metallocene catalyst composition in the production of an isotactic ethylene propylene co-polymer. The composition comprises a metallocene component supported on a particulate silica support having average particle size of 10-40 microns, a pore volume of 1.3-1.6 ml/g, a surface area of 200-400 m 2/g. An alkylalumoxane cocatalyst component is incorporated on the support. The isospecific metallocene is characterized by the formula: B(CpRaRb)(FlR′2)MQn (1) or by the formula: B′(Cp′R′aR′b)(Fl′)M′Q′n′ (2) In the formulas Cp and Cp′ are substituted cyclopentadienyl groups, Fl and Fl′ are fluorenyl groups, and B and B′ are structural bridges. R′ are substituents at the 2 and 7 positions, Ra and R′a are substituents distal to the bridge, and Rb and R′b are proximal to the bridge. M and M′ are transition metals, Q′ is a halogen or a C1-C4 alkyl group; and n′ is an integer of from 0-4.
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